Resonance Photoluminescence Enhancement of Monolayer MoS via a Plasmonic Nanowire Dimer Optical Antenna.

Two-dimensional transition-metal dichalcogenides (TMDs) such as monolayer MoS exhibit remarkable optical properties. However, the intrinsic absorption and emission rates of MoS are very low, thus severely hindering its application in electronics and photonics. Combining MoS with a plasmonic optical antenna is an alternative solution to enhance the emission rates of the 2D semiconductor, and this can drastically increase the photoresponsivity of the corresponding photodetector. Herein, we have constructed a plasmonic gap cavity of a nanowire dimer (NWD) system as an optical antenna to brighten the emission of MoS off the hot spot. Different from the conventional enhancement concept which occurred the plasmonic hot spot, the light emission the nanogap hot spot was thoroughly investigated. We demonstrate that this new plasmonic optical nanostructure leads to a strong enhancement due to the Purcell effect. The NWD optical antenna can trap light to the near field through a high-efficiency plasmonic gap mode (PGM); then the PL emission was enhanced drastically up to 14.5-fold due to the resonance of the plasmonic gap mode (PGM) in the NWD with the excitonic band of monolayer MoS. Theoretical simulations reveal that this NWD can alter the efficiency of convergence and excitation, which was consistent with our experimental results. This study can provide a pathway toward enhancing and controlling PGM-enhanced light emission of TMD materials beyond the plasmonic hot spot.