100th Anniversary of Macromolecular Science Viewpoint: Heterogenous Reversible Deactivation Radical Polymerization at Room Temperature. Recent Advances and Future Opportunities.

Heterogenous reversible deactivation radical polymerization (RDRP) has become an important method for the preparation of a diverse set of well-defined polymer materials in dispersed systems. Conducting heterogeneous RDRP at room temperature seems to be a minor adjustment in polymerization technique but this will lead to a great opportunity for functional polymer synthesis, developing of interesting heterogeneous RDRP systems, and better mechanistic insights into heterogeneous RDRP. In this Viewpoint, we highlight some recent advances of room-temperature heterogeneous RDRP that are challenging to achieve via traditional thermally initiated heterogeneous RDRP. We hope that this Viewpoint can provide some inspiration for both experts in this field and new comers, as well as nonexperts who are interested in preparing their own polymer materials by conducting room-temperature heterogeneous RDRP.