• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

利用涂层腐蚀试验研究二次冶金熔渣对氧化铝-尖晶石耐火材料的侵蚀

Corrosion of Alumina-Spinel Refractory by Secondary Metallurgical Slag Using Coating Corrosion Test.

作者信息

Darban Sina, Reynaert Camille, Ludwig Maciej, Prorok Ryszard, Jastrzębska Ilona, Szczerba Jacek

机构信息

Department of Ceramics and Refractories, Faculty of Materials Science and Ceramics, AGH University of Science and Technology, al. A. Mickiewicza 30, 30-059 Krakow, Poland.

Laboratoire Matériaux et Durabilité des Constructions, INSA/UPS Génie Civil, Université de Toulouse, CEDEX 04, 31077 Toulouse, France.

出版信息

Materials (Basel). 2022 May 10;15(10):3425. doi: 10.3390/ma15103425.

DOI:10.3390/ma15103425
PMID:35629455
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9146358/
Abstract

In this paper, the corrosion mechanism of commercial alumina-spinel refractory was investigated at 1350 and 1450 °C. Disc samples were coated with shells of two different slags containing 4 and 10 wt.% SiO. The after-corrosion refractory was investigated in view of changes in its microstructure and phase composition by SEM/EDS and XRD techniques, respectively. At 1350 °C slags slightly infiltrated the microstructure, whereas at 1450 °C slags infiltrated the alumina-spinel refractory causing its significant corrosion. As a result of corrosion, new phases were formed, including calcium dialuminate (CaAlO), calcium hexaluminate (CaAlO), and gehlenite (CaAlSiO). Formation of calcium aluminate layers in the microstructure of the refractory inhibited further dissolution of alumina aggregates; however, expansive behavior of CaAlO raised the microstructure porosity. The additional SiO in the slag doubled the amount of low melting gehlenite in the matrix, accelerating the corrosion process of alumina-spinel brick at high temperatures.

摘要

本文研究了工业氧化铝-尖晶石耐火材料在1350℃和1450℃下的腐蚀机理。将圆盘试样涂上含有4 wt.%和10 wt.% SiO的两种不同炉渣的壳层。分别通过扫描电子显微镜/能谱仪（SEM/EDS）和X射线衍射仪（XRD）技术，从其微观结构和相组成的变化方面对腐蚀后的耐火材料进行了研究。在1350℃时，炉渣轻微渗入微观结构，而在1450℃时，炉渣渗入氧化铝-尖晶石耐火材料，导致其显著腐蚀。腐蚀的结果是形成了新的相，包括二铝酸钙（CaAlO）、六铝酸钙（CaAlO）和钙黄长石（CaAlSiO）。耐火材料微观结构中铝酸钙层的形成抑制了氧化铝聚集体的进一步溶解；然而，CaAlO的膨胀行为增加了微观结构的孔隙率。炉渣中额外的SiO使基体中低熔点钙黄长石的量增加了一倍，加速了氧化铝-尖晶石砖在高温下的腐蚀过程。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/05238599ac45/materials-15-03425-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/36efdb882f61/materials-15-03425-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/ae554aa51066/materials-15-03425-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/1d0e056d6a9f/materials-15-03425-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/e4a9f0a82ec8/materials-15-03425-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/dafd980f7e73/materials-15-03425-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/409177024693/materials-15-03425-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/7b77c71862b9/materials-15-03425-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/92c6649aeced/materials-15-03425-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/fd69c219da39/materials-15-03425-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/9ec1c29e36d8/materials-15-03425-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/bbde3c46fe8a/materials-15-03425-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/4b18070e4722/materials-15-03425-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/1cfdd4498873/materials-15-03425-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/810ec906ff13/materials-15-03425-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/40e4e1e51077/materials-15-03425-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/461689fc754e/materials-15-03425-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/52ac5688f714/materials-15-03425-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/42a81e145251/materials-15-03425-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/05238599ac45/materials-15-03425-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/36efdb882f61/materials-15-03425-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/ae554aa51066/materials-15-03425-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/1d0e056d6a9f/materials-15-03425-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/e4a9f0a82ec8/materials-15-03425-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/dafd980f7e73/materials-15-03425-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/409177024693/materials-15-03425-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/7b77c71862b9/materials-15-03425-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/92c6649aeced/materials-15-03425-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/fd69c219da39/materials-15-03425-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/9ec1c29e36d8/materials-15-03425-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/bbde3c46fe8a/materials-15-03425-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/4b18070e4722/materials-15-03425-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/1cfdd4498873/materials-15-03425-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/810ec906ff13/materials-15-03425-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/40e4e1e51077/materials-15-03425-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/461689fc754e/materials-15-03425-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/52ac5688f714/materials-15-03425-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/42a81e145251/materials-15-03425-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e481/9146358/05238599ac45/materials-15-03425-g019.jpg

相似文献

1
Corrosion of Alumina-Spinel Refractory by Secondary Metallurgical Slag Using Coating Corrosion Test.利用涂层腐蚀试验研究二次冶金熔渣对氧化铝-尖晶石耐火材料的侵蚀
Materials (Basel). 2022 May 10;15(10):3425. doi: 10.3390/ma15103425.
2
Application of Liquidus Projections in SiO-AlO-CaO Systems with FeO and VO to Study the Dissolution of Alumina Crucibles in Gasification Slags Containing Vanadium.利用液相线投影法研究FeO和VO存在下SiO-AlO-CaO体系中含钒气化熔渣对氧化铝坩埚的侵蚀作用
ACS Omega. 2024 Jan 23;9(5):5345-5360. doi: 10.1021/acsomega.3c06467. eCollection 2024 Feb 6.
3
Corrosion Resistance of MgO and CrO-Based Refractory Raw Materials to PbO-Rich Cu Slag Determined by Hot-Stage Microscopy and Pellet Corrosion Test.通过热台显微镜和球团腐蚀试验测定MgO和CrO基耐火原料对富PbO铜渣的耐腐蚀性。
Materials (Basel). 2022 Jan 18;15(3):725. doi: 10.3390/ma15030725.
4
Optimization of Properties for Alumina-Spinel Refractory Castables by CMA (CaO-MgO-AlO) Aggregates.通过CMA（CaO-MgO-Al₂O₃）骨料优化氧化铝-尖晶石耐火浇注料的性能
Materials (Basel). 2021 Jun 3;14(11):3050. doi: 10.3390/ma14113050.
5
MgO-ZrO Ceramic Composites for Silicomanganese Production.用于硅锰生产的氧化镁 - 氧化锆陶瓷复合材料
Materials (Basel). 2022 Mar 25;15(7):2421. doi: 10.3390/ma15072421.
6
Adverse Effects of Using Metallurgical Slags as Supplementary Cementitious Materials and Aggregate: A Review.使用冶金矿渣作为辅助胶凝材料和骨料的不良反应：综述
Materials (Basel). 2022 May 26;15(11):3803. doi: 10.3390/ma15113803.
7
Corrosion Resistance of Novel Fly Ash-Based Forsterite-Spinel Refractory Ceramics.新型粉煤灰基镁橄榄石-尖晶石耐火陶瓷的耐腐蚀性
Materials (Basel). 2022 Feb 12;15(4):1363. doi: 10.3390/ma15041363.
8
Enhanced Properties of Tailored Alumina-Magnesia-Based Dry Ramming Mixes by Calcium Magnesium Aluminate (CMA).通过铝酸钙镁（CMA）增强定制的氧化铝 - 氧化镁基干式捣打料的性能。
Materials (Basel). 2023 Feb 17;16(4):1707. doi: 10.3390/ma16041707.
9
Iron Removal from Metallurgical Grade Silicon Melts Using Synthetic Slags and Oxygen Injection.使用合成熔渣和氧气注入从冶金级硅熔体中除铁
Materials (Basel). 2022 Sep 1;15(17):6042. doi: 10.3390/ma15176042.
10
Effect of Phase Composition on Leaching Behavior and Mechanical Properties of Ceramics from Ferrochrome Slag and Tundish Slag.相组成对铬铁渣和中间包渣陶瓷浸出行为及力学性能的影响
Materials (Basel). 2022 Mar 8;15(6):1993. doi: 10.3390/ma15061993.

引用本文的文献

1
Design, Manufacturing and Properties of Refractory Materials.耐火材料的设计、制造与性能
Materials (Basel). 2024 Apr 5;17(7):1673. doi: 10.3390/ma17071673.
2
Reaction Mechanism of CA, AlO and CA-AlO Refractories with Refining Slag.CA、AlO及CA-AlO耐火材料与精炼渣的反应机理
Materials (Basel). 2022 Sep 30;15(19):6779. doi: 10.3390/ma15196779.