Department of Inorganic Chemistry, University of Santiago de Compostela, E-15702 Santiago de Compostela, Spain.
Molecules. 2022 May 14;27(10):3146. doi: 10.3390/molecules27103146.
Treatment of the imines with palladium(II) acetate in acetic acid yielded the μ-acetate dinuclear complexes , which readily reacted with sodium chloride or bromide to provide μ-halide analogues. The reaction of the latter with nitrogen, phosphorus and oxygen donor nucleophiles yielded new imine palladacycles following the cleavage of the PdX unit. The complexes were fully characterized by microanalysis, H, C and P NMR spectroscopies, as appropriate. The compounds were applied as catalysts in the Suzuki-Miyaura coupling reaction in aqueous and semi-aqueous media.
用醋酸钯(II)在醋酸中处理亚胺，得到μ-醋酸二核配合物，它们很容易与氯化钠或溴化钠反应，提供μ-卤化物类似物。后者与氮、磷和氧给体亲核试剂反应，在 PdX 单元断裂后生成新的亚胺钯环。这些配合物通过微量分析、H、C 和 P NMR 光谱学进行了充分的表征。这些化合物被用作水相和半水相介质中的 Suzuki-Miyaura 偶联反应的催化剂。
