Polymer Microstructures Self-Assemble on Single-Walled Carbon Nanotube Thin Films.

The formation of self-assembled microstructures of anionic polyelectrolyte, poly(acrylic acid) salts, on the surface of single-walled carbon nanotube thin films was studied by a fast phase separation process that filtrated a mixed dispersion composed of single-walled carbon nanotubes and poly(acrylic acid) derivatives on a membrane filter. The resulting microstructures of poly(acrylic acid) self-assembly were characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, element mapping, and diffuse reflectance Fourier transform infrared spectroscopy. The influence factors including substrate, ion species, single-walled carbon nanotubes, and different kinds of carbon nanotubes were discussed comprehensively for the formation of microstructures of PAA self-assembly by a liquid-liquid phase separation.