在碳纳米管纳米反应器内组装环形磷
Assembly of Ring-Shaped Phosphorus within Carbon Nanotube Nanoreactors.
机构信息
Center of Nanomaterials for Renewable Energy, State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, P.R. China.
The School of Electronic and Information Engineering and State Key Laboratory for Mechanical Behaviour of Materials, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, P.R. China.
出版信息
Angew Chem Int Ed Engl. 2017 Feb 6;56(7):1850-1854. doi: 10.1002/anie.201611740. Epub 2017 Jan 11.
A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P and P structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5-8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient conditions. The nanostructures were characterized by high-resolution transmission electron microscopy, scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, Raman scattering, attenuated total reflectance Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.
一种迄今为止尚未被观察到的磷同素异形体，即由交替的 P 和 P 结构单元组成的环形磷，已经通过在 500°C 时对红磷进行化学气相输运和反应，在 5-8nm 内径的多壁碳纳米管纳米反应器中组装而成。具有环绕石墨烯壁的环形纳米结构在环境条件下是稳定的。这些纳米结构通过高分辨率透射电子显微镜、扫描透射电子显微镜、能量色散 X 射线能谱、拉曼散射、衰减全反射傅里叶变换红外光谱和 X 射线光电子能谱进行了表征。
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