• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

光响应性聚氨酯：光响应基团的分类、光响应反应及其应用。

Light-responsive polyurethanes: classification of light-responsive moieties, light-responsive reactions, and their applications.

作者信息

Lam Ki Yan, Lee Choy Sin, Pichika Mallikarjuna Rao, Cheng Sit Foon, Hang Tan Rachel Yie

机构信息

School of Postgraduate, International Medical University No. 126, Jalan Jalil Perkasa 19, Bukit Jalil 57000 Kuala Lumpur Malaysia

Department of Pharmaceutical Chemistry, School of Pharmacy, International Medical University No. 126, Jalan Jalil Perkasa 19, Bukit Jalil 57000 Kuala Lumpur Malaysia.

出版信息

RSC Adv. 2022 May 19;12(24):15261-15283. doi: 10.1039/d2ra01506d. eCollection 2022 May 17.

DOI:10.1039/d2ra01506d
PMID:35693222
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9118056/
Abstract

Stimuli responsiveness has been an attractive feature of smart material design, wherein the chemical and physical properties of the material can be varied in response to small environmental change. Polyurethane (PU), a widely used synthetic polymer can be upgraded into a light-responsive smart polymer by introducing a light-sensitive moiety into the polymer matrix. For instance, azobenzene, spiropyran, and coumarin result in reversible light-induced reactions, while -nitrobenzyl can result in irreversible light-induced reactions. These variations of light-stimulus properties endow PU with wide ranges of physical, mechanical, and chemical changes upon exposure to different wavelengths of light. PU responsiveness has rarely been reviewed even though it is known to be one of the most versatile polymers with diverse ranges of applications in household, automotive, electronic, construction, medical, and biomedical industries. This review focuses on the classes of light-responsive moieties used in PU systems, their synthesis, and the response mechanism of light-responsive PU-based materials, which also include dual- or multi-responsive light-responsive PU systems. The advantages and limitations of light-responsive PU are reviewed and challenges in the development of light-responsive PU are discussed.

摘要

刺激响应性一直是智能材料设计的一个吸引人的特性，其中材料的化学和物理性质可以响应微小的环境变化而改变。聚氨酯（PU）是一种广泛使用的合成聚合物，通过将光敏部分引入聚合物基体中，可以将其升级为光响应智能聚合物。例如，偶氮苯、螺吡喃和香豆素会引发可逆的光诱导反应，而对硝基苄基会引发不可逆的光诱导反应。这些光刺激性质的变化使聚氨酯在暴露于不同波长的光时具有广泛的物理、机械和化学变化。尽管聚氨酯是已知用途最广泛的聚合物之一，在家庭、汽车、电子、建筑、医疗和生物医学行业有多种应用，但聚氨酯的响应性很少被综述。本综述重点关注聚氨酯体系中使用的光响应部分的类别、它们的合成以及光响应聚氨酯的响应机制，其中还包括双响应或多响应光响应聚氨酯体系。综述了光响应聚氨酯的优点和局限性，并讨论了光响应聚氨酯开发中的挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/78a461d5d739/d2ra01506d-p5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/541076d1f177/d2ra01506d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/35511aa7dd9d/d2ra01506d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/64baecf89a09/d2ra01506d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/66e9818bf5d2/d2ra01506d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/ffb927496d70/d2ra01506d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/0ceaf627515b/d2ra01506d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/7e17f969495d/d2ra01506d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/5b3eafca7e9b/d2ra01506d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/34d17ae5e977/d2ra01506d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/d0703b4b956e/d2ra01506d-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/254f7154748e/d2ra01506d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/7271ecee7ce4/d2ra01506d-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/feae02318405/d2ra01506d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/9b7a8c823b78/d2ra01506d-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/a45249bf230a/d2ra01506d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/4f9af6afa9eb/d2ra01506d-s6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/5f300ffd2064/d2ra01506d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/c9fb47facb68/d2ra01506d-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/899271142641/d2ra01506d-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/ae213d4a925a/d2ra01506d-s7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/50605b489f58/d2ra01506d-s8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/4a755d2c83ca/d2ra01506d-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/abf782aa7d52/d2ra01506d-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/19db36cfcde5/d2ra01506d-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/4fcefef80fa8/d2ra01506d-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/f447ab625c37/d2ra01506d-p4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/78a461d5d739/d2ra01506d-p5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/541076d1f177/d2ra01506d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/35511aa7dd9d/d2ra01506d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/64baecf89a09/d2ra01506d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/66e9818bf5d2/d2ra01506d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/ffb927496d70/d2ra01506d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/0ceaf627515b/d2ra01506d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/7e17f969495d/d2ra01506d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/5b3eafca7e9b/d2ra01506d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/34d17ae5e977/d2ra01506d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/d0703b4b956e/d2ra01506d-s3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/254f7154748e/d2ra01506d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/7271ecee7ce4/d2ra01506d-s4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/feae02318405/d2ra01506d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/9b7a8c823b78/d2ra01506d-s5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/a45249bf230a/d2ra01506d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/4f9af6afa9eb/d2ra01506d-s6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/5f300ffd2064/d2ra01506d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/c9fb47facb68/d2ra01506d-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/899271142641/d2ra01506d-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/ae213d4a925a/d2ra01506d-s7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/50605b489f58/d2ra01506d-s8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/4a755d2c83ca/d2ra01506d-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/abf782aa7d52/d2ra01506d-p1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/19db36cfcde5/d2ra01506d-p2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/4fcefef80fa8/d2ra01506d-p3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/f447ab625c37/d2ra01506d-p4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e363/9118056/78a461d5d739/d2ra01506d-p5.jpg

相似文献

1
Light-responsive polyurethanes: classification of light-responsive moieties, light-responsive reactions, and their applications.光响应性聚氨酯：光响应基团的分类、光响应反应及其应用。
RSC Adv. 2022 May 19;12(24):15261-15283. doi: 10.1039/d2ra01506d. eCollection 2022 May 17.
2
NIR-induced photothermal-responsive shape memory polyurethane for versatile smart material applications.用于多功能智能材料应用的近红外诱导光热响应形状记忆聚氨酯。
RSC Adv. 2024 Aug 5;14(33):24265-24286. doi: 10.1039/d4ra04754k. eCollection 2024 Jul 26.
3
Stimuli-Responsive Crystalline Smart Materials: From Rational Design and Fabrication to Applications.刺激响应性晶体智能材料：从合理设计与制备到应用
Acc Chem Res. 2022 Apr 5;55(7):1047-1058. doi: 10.1021/acs.accounts.2c00027. Epub 2022 Mar 16.
4
Light-, temperature-, and pH-responsive micellar assemblies of spiropyran-initiated amphiphilic block copolymers: Kinetics of photochromism, responsiveness, and smart drug delivery.基于螺吡喃引发的两亲嵌段共聚物的光、温度和 pH 响应胶束组装：光致变色动力学、响应性和智能药物递送。
Mater Sci Eng C Mater Biol Appl. 2020 Apr;109:110524. doi: 10.1016/j.msec.2019.110524. Epub 2019 Dec 7.
5
Recent Trends in Applying Rrtho-Nitrobenzyl Esters for the Design of Photo-Responsive Polymer Networks.用于光响应聚合物网络设计的邻硝基苄酯应用的最新趋势。
Materials (Basel). 2020 Jun 19;13(12):2777. doi: 10.3390/ma13122777.
6
Synthesis and Characterization of Dual Stimuli-Sensitive Biodegradable Polyurethane Soft Hydrogels for 3D Cell-Laden Bioprinting.双重刺激响应型可生物降解聚氨酯软水凝胶的合成与表征及其用于 3D 细胞打印。
ACS Appl Mater Interfaces. 2018 Sep 5;10(35):29273-29287. doi: 10.1021/acsami.8b08362. Epub 2018 Aug 22.
7
Polyurethanes Modified by Ionic Liquids and Their Applications.离子液体改性聚氨酯及其应用。
Int J Mol Sci. 2023 Jul 19;24(14):11627. doi: 10.3390/ijms241411627.
8
Magneto-electro-responsive material based on magnetite nanoparticles/polyurethane composites.基于磁铁矿纳米粒子/聚氨酯复合材料的磁电响应材料。
Mater Sci Eng C Mater Biol Appl. 2016 Apr 1;61:312-23. doi: 10.1016/j.msec.2015.12.014. Epub 2015 Dec 12.
9
Recent advances in tissue engineering scaffolds based on polyurethane and modified polyurethane.基于聚氨酯及改性聚氨酯的组织工程支架的最新进展
Mater Sci Eng C Mater Biol Appl. 2021 Jan;118:111228. doi: 10.1016/j.msec.2020.111228. Epub 2020 Aug 8.
10
A New Class of Mechano-Responsive Polyurethane Via Anthracene -TAD Diels-Alder (DA) Click Chemistry.通过蒽-TAD狄尔斯-阿尔德（DA）点击化学合成的新型机械响应性聚氨酯
Small. 2024 Nov;20(48):e2406866. doi: 10.1002/smll.202406866. Epub 2024 Sep 11.

引用本文的文献

1
Facile Ester-based Phase Change Materials Synthesis for Enhanced Energy Storage Toward Battery Thermal Management.用于增强电池热管理储能的基于酯的相变材料的简便合成
Adv Sci (Weinh). 2025 Mar;12(9):e2413703. doi: 10.1002/advs.202413703. Epub 2025 Jan 13.
2
Thermal Conductivity of Polymers: A Simple Matter Where Complexity Matters.聚合物的热导率：一个复杂性起关键作用的简单问题。
Macromol Rapid Commun. 2024 Dec;45(24):e2400517. doi: 10.1002/marc.202400517. Epub 2024 Oct 18.
3
A comprehensive review of intelligent controlled release antimicrobial packaging in food preservation.

本文引用的文献

1
Mechanochemical Activation of Covalent Bonds in Polymers with Full and Repeatable Macroscopic Shape Recovery.具有完全且可重复的宏观形状恢复能力的聚合物中共价键的机械化学活化
ACS Macro Lett. 2014 Mar 18;3(3):216-219. doi: 10.1021/mz500031q. Epub 2014 Feb 12.
2
Photodirected Formation and Control of Wrinkles on a Thiol-ene Elastomer.硫醇-烯弹性体上皱纹的光控形成与调控
ACS Macro Lett. 2013 Jun 18;2(6):474-477. doi: 10.1021/mz400166e. Epub 2013 May 14.
3
Reversible photo-responsive gel-sol transitions of robust organogels based on an azobenzene-containing main-chain liquid crystalline polymer.
食品保鲜中智能控释抗菌包装的综合综述。
Food Sci Biotechnol. 2023 Jun 3;32(11):1459-1478. doi: 10.1007/s10068-023-01344-8. eCollection 2023 Oct.
基于含偶氮苯主链液晶聚合物的坚固有机凝胶的可逆光响应凝胶-溶胶转变
RSC Adv. 2020 Jan 22;10(7):3726-3733. doi: 10.1039/c9ra10161f.
4
Photosensitive Supramolecular Micelle-Mediated Cellular Uptake of Anticancer Drugs Enhances the Efficiency of Chemotherapy.光敏超分子胶束介导的抗癌药物细胞摄取增强了化疗的效率。
Int J Mol Sci. 2020 Jun 30;21(13):4677. doi: 10.3390/ijms21134677.
5
Construction of coumarin-based cross-linked micelles with pH responsive hydrazone bond and tumor targeting moiety.构建具有pH响应腙键和肿瘤靶向部分的香豆素基交联胶束。
J Mater Chem B. 2016 Feb 28;4(8):1480-1488. doi: 10.1039/c5tb02729b. Epub 2016 Feb 4.
6
A high water-content and high elastic dual-responsive polyurethane hydrogel for drug delivery.一种用于药物递送的高含水量和高弹性双响应聚氨酯水凝胶。
J Mater Chem B. 2015 Nov 14;3(42):8401-8409. doi: 10.1039/c5tb01702e. Epub 2015 Sep 25.
7
Dual pH-responsive charge-reversal and photo-crosslinkable polymer nanoparticles for controlled drug release.双 pH 响应电荷反转和光交联聚合物纳米粒子用于控制药物释放。
J Biomater Sci Polym Ed. 2020 May;31(7):849-868. doi: 10.1080/09205063.2020.1725279. Epub 2020 Feb 16.
8
Organic semiconducting polymer amphiphile for near-infrared-II light-triggered phototheranostics.用于近红外-II 光触发光热治疗的有机半导体聚合物两亲物。
Biomaterials. 2020 Feb;232:119684. doi: 10.1016/j.biomaterials.2019.119684. Epub 2019 Dec 13.
9
Crown- and phosphoryl-containing metal phthalocyanines in solutions of poly(N-vinylpyrrolidone): Supramolecular organization, accumulation in cells, photo-induced generation of reactive oxygen species, and cytotoxicity.冠醚和含磷金属酞菁在聚（N-乙烯基吡咯烷酮）溶液中的超分子结构、在细胞中的积累、光诱导活性氧的生成和细胞毒性。
J Photochem Photobiol B. 2020 Jan;202:111722. doi: 10.1016/j.jphotobiol.2019.111722. Epub 2019 Nov 23.
10
Poly(ε-caprolactone) (PCL) Hollow Nanoparticles with Surface Sealability and On-Demand Pore Generability for Easy Loading and NIR Light-Triggered Release of Drug.具有表面密封性和按需产生孔隙能力的聚（ε-己内酯）（PCL）中空纳米颗粒，便于药物的装载和近红外光触发释放
Pharmaceutics. 2019 Oct 13;11(10):528. doi: 10.3390/pharmaceutics11100528.