• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

可见光照度条件下的水相光氧化还原催化

Visible-Light Photoredox Catalysis in Water.

机构信息

Department of Pharmacy, University of Naples Federico II, via D. Montesano 49, 80131 Napoli, Italy.

Department of Drug Science, University of Piemonte Orientale, Largo Donegani 2, 28100 Novara, Italy.

出版信息

J Org Chem. 2023 May 19;88(10):6284-6293. doi: 10.1021/acs.joc.2c00805. Epub 2022 Jun 14.

DOI:10.1021/acs.joc.2c00805
PMID:35700388
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10204095/
Abstract

The use of water in organic synthesis draws attention to its green chemistry features and its unique ability to unveil unconventional reactivities. Herein, literature about the use of water as a reaction medium under visible-light photocatalytic conditions is summarized in order to highlight challenges and opportunities. Accordingly, this Synopsis has been divided into four different sections focused on (1) the unconventional role of water in photocatalytic reactions, (2) -/water reactions, (3) water-soluble photocatalysts, and (4) photomicellar catalytic systems.

摘要

水在有机合成中的应用引起了人们对其绿色化学特性和揭示非常规反应性的独特能力的关注。本文总结了在可见光光催化条件下使用水作为反应介质的文献，以突出挑战和机遇。因此，本概要分为四个不同的部分，分别侧重于（1）水在光催化反应中的非常规作用，（2）-/水反应，（3）水溶性光催化剂，和（4）光胶束催化体系。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/5ca9ead5c7db/jo2c00805_0031.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/b0b72f750340/jo2c00805_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/7e459dbaf21a/jo2c00805_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/d7b8cc212f6f/jo2c00805_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/3ab7c48730d4/jo2c00805_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/abeafd43970f/jo2c00805_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/f740691cdf7a/jo2c00805_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/070f392c14c7/jo2c00805_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/605d7884c5f4/jo2c00805_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/15b82d710aca/jo2c00805_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/092e353fba55/jo2c00805_0015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/4d2f80c6a854/jo2c00805_0016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/17419f739672/jo2c00805_0017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/6bbf51acfcc5/jo2c00805_0018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/da25eb88e95d/jo2c00805_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/2579fc399e47/jo2c00805_0019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/a3baf1c92741/jo2c00805_0020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/98ebc36ea539/jo2c00805_0021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/c98f12d35131/jo2c00805_0022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/35694729f226/jo2c00805_0023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/f89d76ed8353/jo2c00805_0024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/fcbc9d48f417/jo2c00805_0025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/b501a999e215/jo2c00805_0026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/d70389d661c4/jo2c00805_0027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/407396471586/jo2c00805_0028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/84f669abba42/jo2c00805_0029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/3b733e88adaa/jo2c00805_0030.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/5ca9ead5c7db/jo2c00805_0031.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/b0b72f750340/jo2c00805_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/7e459dbaf21a/jo2c00805_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/d7b8cc212f6f/jo2c00805_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/3ab7c48730d4/jo2c00805_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/abeafd43970f/jo2c00805_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/f740691cdf7a/jo2c00805_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/070f392c14c7/jo2c00805_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/605d7884c5f4/jo2c00805_0013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/15b82d710aca/jo2c00805_0014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/092e353fba55/jo2c00805_0015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/4d2f80c6a854/jo2c00805_0016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/17419f739672/jo2c00805_0017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/6bbf51acfcc5/jo2c00805_0018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/da25eb88e95d/jo2c00805_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/2579fc399e47/jo2c00805_0019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/a3baf1c92741/jo2c00805_0020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/98ebc36ea539/jo2c00805_0021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/c98f12d35131/jo2c00805_0022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/35694729f226/jo2c00805_0023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/f89d76ed8353/jo2c00805_0024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/fcbc9d48f417/jo2c00805_0025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/b501a999e215/jo2c00805_0026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/d70389d661c4/jo2c00805_0027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/407396471586/jo2c00805_0028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/84f669abba42/jo2c00805_0029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/3b733e88adaa/jo2c00805_0030.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/369d/10204095/5ca9ead5c7db/jo2c00805_0031.jpg

相似文献

1
Visible-Light Photoredox Catalysis in Water.可见光照度条件下的水相光氧化还原催化
J Org Chem. 2023 May 19;88(10):6284-6293. doi: 10.1021/acs.joc.2c00805. Epub 2022 Jun 14.
2
Merging Visible Light Photoredox and Gold Catalysis.可见光光氧化还原与金催化的融合。
Acc Chem Res. 2016 Oct 18;49(10):2261-2272. doi: 10.1021/acs.accounts.6b00351. Epub 2016 Sep 9.
3
Asymmetric photoredox transition-metal catalysis activated by visible light.可见光激活的不对称光氧化还原过渡金属催化。
Nature. 2014 Nov 6;515(7525):100-3. doi: 10.1038/nature13892.
4
Exploration of Visible-Light Photocatalysis in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond.可见光催化在杂环合成与功能化中的应用探索：反应设计及其他。
Acc Chem Res. 2016 Sep 20;49(9):1911-23. doi: 10.1021/acs.accounts.6b00254. Epub 2016 Aug 23.
5
Mechanistic Perspectives on Organic Photoredox Catalysis for Aromatic Substitutions.有机光氧化还原催化芳香取代反应的机理研究。
Acc Chem Res. 2016 Oct 18;49(10):2316-2327. doi: 10.1021/acs.accounts.6b00293. Epub 2016 Sep 26.
6
Merging Visible Light Photoredox Catalysis with Metal Catalyzed C-H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants.可见光光氧化还原催化与金属催化 C-H 活化的融合：以氧和超氧离子作为氧化剂的作用。
Acc Chem Res. 2016 Sep 20;49(9):1969-79. doi: 10.1021/acs.accounts.6b00275. Epub 2016 Aug 24.
7
Controlled Fluoroalkylation Reactions by Visible-Light Photoredox Catalysis.可见光光氧化还原催化控制的氟烷基化反应。
Acc Chem Res. 2016 Oct 18;49(10):2284-2294. doi: 10.1021/acs.accounts.6b00248. Epub 2016 Sep 14.
8
Photochemical Stereocontrol Using Tandem Photoredox-Chiral Lewis Acid Catalysis.光化学立体控制的串联光氧化还原-手性路易斯酸催化。
Acc Chem Res. 2016 Oct 18;49(10):2307-2315. doi: 10.1021/acs.accounts.6b00280. Epub 2016 Aug 9.
9
CO -Triggered Switchable Hydrophilicity of a Heterogeneous Conjugated Polymer Photocatalyst for Enhanced Catalytic Activity in Water.CO 触发的杂化共轭聚合物光催化剂的可切换亲水性，提高水相中的催化活性。
Angew Chem Int Ed Engl. 2018 Mar 5;57(11):2967-2971. doi: 10.1002/anie.201711773. Epub 2018 Feb 14.
10
Oxyethylated Fluoresceine-(thia)calix[4]arene Conjugates: Synthesis and Visible-Light Photoredox Catalysis in Water-Organic Media.乙氧基化荧光素-(硫代)杯[4]芳烃衍生物：在水-有机溶剂中的可见光光氧化还原催化合成。
Molecules. 2022 Dec 28;28(1):261. doi: 10.3390/molecules28010261.

引用本文的文献

1
Diblock Copolypeptoid Micelles as Platform for Aqueous Photoredox Cyanation of Arenes.二嵌段共聚肽类胶束作为芳烃水相光催化氧化氰化反应的平台
J Am Chem Soc. 2025 Aug 13;147(32):29152-29161. doi: 10.1021/jacs.5c07882. Epub 2025 Aug 4.
2
Visible-light photoredox catalysis of polydopamine with triethanolamine in water.水中聚多巴胺与三乙醇胺的可见光光氧化还原催化作用
Chem Sci. 2025 Jul 22. doi: 10.1039/d5sc04938e.
3
Dawn of photoredox catalysis.光氧化还原催化的黎明。

本文引用的文献

1
Photomicellar Catalyzed Synthesis of Amides from Isocyanides: Optimization, Scope, and NMR Studies of Photocatalyst/Surfactant Interactions.光胶束催化异腈合成酰胺：光催化剂/表面活性剂相互作用的优化、范围及核磁共振研究
ACS Org Inorg Au. 2021 Nov 11;2(1):66-74. doi: 10.1021/acsorginorgau.1c00028. eCollection 2022 Feb 2.
2
Photoredox-Catalyzed Reduction of Halogenated Arenes in Water by Amphiphilic Polymeric Nanoparticles.光氧化还原催化的水相卤代芳烃还原反应。
Molecules. 2021 Sep 28;26(19):5882. doi: 10.3390/molecules26195882.
3
Water as the reaction medium in organic chemistry: from our worst enemy to our best friend.
Proc Jpn Acad Ser B Phys Biol Sci. 2025;101(5):274-301. doi: 10.2183/pjab.101.019.
4
Water Effect on the Photochemistry of Arylazo Sulfonates.水对芳基偶氮磺酸盐光化学的影响。
J Org Chem. 2025 May 23;90(20):6726-6736. doi: 10.1021/acs.joc.5c00314. Epub 2025 Apr 30.
5
Photocatalyzed elaboration of antibody-based bioconjugates.基于抗体的生物共轭物的光催化制备
Beilstein J Org Chem. 2025 Mar 18;21:616-629. doi: 10.3762/bjoc.21.49. eCollection 2025.
6
Photomechanochemistry: harnessing mechanical forces to enhance photochemical reactions.光机械化学：利用机械力增强光化学反应。
Beilstein J Org Chem. 2025 Mar 3;21:458-472. doi: 10.3762/bjoc.21.33. eCollection 2025.
7
Supramolecular self-assembly of metal complex surfactants (MeCS) into micellar nanoscale reactors in aqueous solution.金属配合物表面活性剂（MeCS）在水溶液中自组装形成胶束纳米级反应器。
Chem Sci. 2025 Feb 10;16(8):3440-3446. doi: 10.1039/d4sc07623k. eCollection 2025 Feb 19.
8
Efficacy of radical reactions of isocyanides with heteroatom radicals in organic synthesis.异腈与杂原子自由基的自由基反应在有机合成中的功效。
Beilstein J Org Chem. 2024 Aug 26;20:2114-2128. doi: 10.3762/bjoc.20.182. eCollection 2024.
9
Visible-Light-Induced Dearomative Annulation of Indoles toward Stereoselective Formation of Fused- and Spiro Indolines.可见光诱导吲哚的去芳构化环化反应以立体选择性地形成稠合和螺环吲哚啉。
ACS Omega. 2024 Aug 13;9(34):36023-36042. doi: 10.1021/acsomega.4c02848. eCollection 2024 Aug 27.
10
Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop.光催化的挑战与未来展望：跨学科研讨会的结论
JACS Au. 2024 Aug 8;4(8):2746-2766. doi: 10.1021/jacsau.4c00527. eCollection 2024 Aug 26.
水在有机化学中作为反应介质：从我们最大的敌人到我们最好的朋友。
Chem Sci. 2021 Feb 12;12(12):4237-4266. doi: 10.1039/d0sc06000c.
4
Aqueous Persistent Noncovalent Ion-Pair Cooperative Coupling in a Ruthenium Cobaltabis(dicarbollide) System as a Highly Efficient Photoredox Oxidation Catalyst.钌钴双（二碳硼烷）体系中作为高效光氧化还原氧化催化剂的水相持久性非共价离子对协同偶联
Inorg Chem. 2021 Jun 21;60(12):8898-8907. doi: 10.1021/acs.inorgchem.1c00751. Epub 2021 Jun 7.
5
Water-Soluble Iridium Photoredox Catalyst for the Trifluoromethylation of Biomolecule Substrates in Phosphate Buffered Saline Solvent.水溶性铱光氧化还原催化剂在磷酸盐缓冲生理盐水溶剂中生物分子底物的三氟甲基化反应。
Org Lett. 2021 May 21;23(10):3823-3827. doi: 10.1021/acs.orglett.1c00871. Epub 2021 Apr 30.
6
Selective photoredox direct arylations of aryl bromides in water in a microfluidic reactor.在微流控反应器中，水相中芳基溴化物的选择性光氧化还原直接芳基化反应。
Org Biomol Chem. 2021 Apr 7;19(13):3016-3023. doi: 10.1039/d1ob00050k. Epub 2021 Mar 22.
7
Photoredox-Catalyzed Addition of Dibromofluoromethane to Alkenes: Direct Synthesis of 1-Bromo-1-fluoroalkanes.光氧化还原催化的二溴氟甲烷与烯烃的加成反应：1-溴-1-氟烷烃的直接合成
Org Lett. 2021 Mar 19;23(6):2364-2369. doi: 10.1021/acs.orglett.1c00639. Epub 2021 Mar 5.
8
Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds.可见光照药物相关化合物的后期功能化中的光催化作用。
Chem Soc Rev. 2021 Jan 21;50(2):766-897. doi: 10.1039/d0cs00493f. Epub 2020 Dec 22.
9
Recent advances on micellar catalysis in water.胶束催化在水中的最新进展。
Adv Colloid Interface Sci. 2021 Jan;287:102299. doi: 10.1016/j.cis.2020.102299. Epub 2020 Oct 27.
10
Noncovalently Linked Metallacarboranes on Functionalized Magnetic Nanoparticles as Highly Efficient, Robust, and Reusable Photocatalysts in Aqueous Medium.功能化磁性纳米颗粒上的非共价连接金属碳硼烷作为水介质中高效、稳健且可重复使用的光催化剂
ACS Appl Mater Interfaces. 2020 Dec 16;12(50):56372-56384. doi: 10.1021/acsami.0c17847. Epub 2020 Dec 7.