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基于钛酸盐纳米管的多相催化剂用于高效生产生物质衍生化学品。

Titanate Nanotubes-Based Heterogeneous Catalyst for Efficient Production of Biomass Derived Chemicals.

作者信息

Zhou Shuolin, Wu Lu, Bai Junzhuo, Liu Xianxiang, Lei Min, Long Min, Huang Keying

机构信息

School of Elementary Education, Changsha Normal University, Changsha, China.

National and Local Joint Engineering Laboratory for New Petro-Chemical Materials and Fine Utilization of Resources, Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, China.

出版信息

Front Chem. 2022 Jun 6;10:939289. doi: 10.3389/fchem.2022.939289. eCollection 2022.

Abstract

The development of efficient heterogeneous catalytic system to convert plentiful biomass to renewable bio-chemicals is urgent need. Titanate nanotubes-based materials obtained from hydrothermal treatment have been reported as low-cost and efficient catalytic materials in chemical syntheses for bio-based chemicals production with interesting catalytic performance. This mini-review expressly revealed the significance and potential of using titanate nanotubes based material as sustainable and environmentally benign solid catalysts/supports for synthesis of various bio-based chemicals, including glycerol-derived solketal, jet fuel range alkanes precursors, biomass-derived esters, aldehydes, aromatic compounds and so on. From the current knowledge on titanate nanotubes-based material via hydrothermal method here summarized, the future lines of research in the field of catalysis/supports for bio-based chemicals production are outlined.

摘要

开发高效的多相催化体系以将丰富的生物质转化为可再生生物化学品是迫切需求。据报道,通过水热法获得的钛酸盐纳米管基材料是低成本且高效的催化材料,在用于生物基化学品生产的化学合成中具有有趣的催化性能。这篇小型综述明确揭示了使用钛酸盐纳米管基材料作为可持续且环境友好的固体催化剂/载体来合成各种生物基化学品的重要性和潜力,这些生物基化学品包括甘油衍生的缩酮、喷气燃料范围的烷烃前体、生物质衍生的酯、醛、芳香族化合物等。基于此处总结的关于通过水热法制备钛酸盐纳米管基材料的现有知识,概述了生物基化学品生产催化/载体领域未来的研究方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/54f6/9207236/7a6329b9e08f/fchem-10-939289-g001.jpg

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