Hydrothermally synthesized titanate nanomaterials for the removal of heavy metals and radionuclides from water: A review.

Hazardous heavy metals and radionuclides in water and wastewater are of drastic concern owing to their detrimental impacts on the organisms as well as the circumambient ecosystem. To remove them as much as we can, both technique and materials were studied in the past years. The adsorption technique as superior water remediation method with the simplicity of design, environmental friendliness and high efficiency was well established. Consequently, it is practically important to explore advanced and economically feasible absorbents for removing these poisonous pollutants from aqueous solutions. So far, large numbers of experiments proved hydrothermally synthesized titanate nanomaterials (TNMs) could be a prospectively excellent adsorbent extracting heavy metals and radionuclides from water due to the high specific surface area, tunable pore size, abundant surface active sites, favorable hydrophilic properties. The objective of this work is to give an overview of hydrothermal synthesis, adsorption performance of TNMs for heavy metals and radionuclides, as well as the various influencing factors for water purification. It comprehensively reviews the structural changes and regenerability of TNMs after adsorption, and different modification methods adopted for improving removal capacity. Additionally, it uniquely highlights the efficient decontamination of the pollutants through a synergistic effect of adsorption and photocatalysis by TNMs. This review provides detailed information for the development, application, and research challenges faced by hydrothermally synthesized TNMs for the removal of heavy metals and radionuclides from aqueous solutions, which will serve as a reference guide for scientists in related fields.