Institute of Energy and Quality, University of Miskolc, 3515, Miskolc, Miskolc-Egyetemváros, Hungary.
Institute of Chemistry, University of Miskolc, 3515, Miskolc, Miskolc-Egyetemváros, Hungary.
Waste Manag. 2022 Jul 15;149:302-312. doi: 10.1016/j.wasman.2022.06.027. Epub 2022 Jun 24.
Consumer society requires the continuous evolution of products, thus generating a lot of waste. The automotive industry has also undergone significant development, generating 1.5 billion used tires worldwide every year. Landfilling of tires is prohibited and their disposal is therefore a major issue. Although many studies deal with the utilization of tire as a fuel, there is limited research that would specifically describe the relationship between pollutant emissions from tire combustion and the relationship between emitted pollutants and firebox temperature. Based on this, this work aims to investigate flue gas concentrations (CO, CO, NO, and SO) and solid pollutants from tire burned in a lab-scale electrical furnace at firebox temperature from 650 to 900 °C. The decomposition of the CaCO filler during the combustion of the tire has been detected with thermal analytical investigation and combustion experiments. In the case of the CO flue gas pollutant, a second maximum concentration is observed due to the presence of CaCO With the increasing firebox temperature, the size of solid particles decreases, and the mesh structure formed becomes denser. At the same time, the concentration of emitted solid PAHs decreases, dominated by aromatic compounds with smaller number of rings. However, the variation of firebox temperature does not affect the amount of benzo(b)fluoranthene and fluoranthene relative to the total concentration.
消费社会需要产品不断进化,从而产生了大量的废物。汽车行业也经历了重大的发展,每年在全球产生 15 亿条废旧轮胎。轮胎的填埋是被禁止的,因此它们的处理是一个主要问题。尽管许多研究都涉及到将轮胎作为燃料的利用,但很少有研究专门描述轮胎燃烧产生的污染物排放与燃烧室温度之间的关系。基于此,这项工作旨在研究在 650 至 900°C 的燃烧室温度下,在实验室规模的电炉中燃烧轮胎时的烟道气浓度(CO、CO2、NO 和 SO)和固体污染物。在轮胎燃烧过程中,通过热分析研究和燃烧实验检测到 CaCO 填料的分解。在 CO 烟道气污染物的情况下,由于 CaCO 的存在,观察到第二个最大浓度。随着燃烧室温度的升高,固体颗粒的尺寸减小,形成的网状结构变得更加致密。同时,排放的固体多环芳烃的浓度降低,以具有较小环数的芳香族化合物为主。然而,燃烧室温度的变化并不影响苯并(b)荧蒽和荧蒽相对于总浓度的含量。