Cyclic heat engines with nonisentropic adiabats and generalization to steady-state devices including thermoelectric converters.

For heat engines (including refrigerators) the separation of total entropy production in reversible parts ΔS and irreversible contributions has proved to be very useful. The ΔS are entropies for ideal lossless processes at the hot- and cold side and are important system parameters. For Carnot-like heat engines performing finite-time cycles, the concern was raised in a preceding paper that the ΔS are not always independent from irreversibilities, if initial and final working fluid temperatures T_{f}(t) differ in the isothermal transitions. It turns out that the ΔS are unchanged and independent, if T_{f} (t) evolution is optimized for entropy minimization and apparent inconsistencies are cleared up. If nonisentropic transitions in the adiabatic cycle branches are taken into account, the difference of cold- and hot-side entropy reversibilities is equal to the entropy production in the adiabats. Maximization of cooling power is studied for various irreversible entropy models. The concepts are extended to noncyclic steady-state engines. Power maximization and efficiency calculations are performed exactly analytically. This serves as prerequisite for the hitherto unsolved problem of an accurate definition of reversible and irreversible entropy parts in thermoelectric (TE) converters in the case of inhomogeneous three-dimensional material distributions. It is revealed that for nonconstant Seebeck coefficients, additional terms to the Joule heat arise that destroy positive generator performance in the limit of heat conductance k→0, in contrast to the traditional constant material properties model. Thus, the concept of improving TE materials by reducing k is in question and an adapted figure of merit Z is presented to deal with the situation.