二铅烷催化的酮和醛的无溶剂无添加剂硼氢化反应
Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes.
作者信息
Zhang Guoqi, Li Sihan, Zeng Haisu, Zheng Shengping, Neary Michelle C
机构信息
Department of Sciences, John Jay College, PhD Program in Chemistry, The Graduate Center, The City University of New York New York NY 10019 USA
Department of Chemistry, Hunter College, The City University of New York New York 10065 NY USA.
出版信息
RSC Adv. 2022 Jun 29;12(30):19086-19090. doi: 10.1039/d2ra03731a.
A new diplumbane, namely [Pb(CHSiMe)], was synthesized and structurally characterized. This group 14 element compound was found to catalyse the hydroboration of ketones and aldehydes under mild conditions without the use of additives and solvents, leading to the synthesis of a range of alcohols in high yields after hydrolysis.
合成并表征了一种新的二铅烷，即[Pb(CHSiMe)]。发现这种第14族元素化合物在温和条件下无需使用添加剂和溶剂就能催化酮和醛的硼氢化反应，水解后能高产率地合成一系列醇类。
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