Holly Haggar Jack Ivan, Ghataora Suneal S, Trinito Valerio, Bai Jie, Wang Tao
Department of Electronic and Electrical Engineering, The University of Sheffield, Sheffield S1 3JD, U.K.
ACS Photonics. 2022 Jul 20;9(7):2378-2384. doi: 10.1021/acsphotonics.2c00414. Epub 2022 Jul 5.
Time-resolved photoluminescence (TRPL) is often used to study the excitonic dynamics of semiconductor optoelectronics such as the carrier recombination lifetime of III-nitride light-emitting diodes (LEDs). However, for any real-world application that requires LEDs under electrical injection, TRPL suffers an intrinsic limitation due to the absence of taking carrier transport effects into account. This becomes a severe issue for III-nitride LEDs used for visible light communication (VLC) since the modulation bandwidth for VLC is determined by the overall carrier lifetime of an LED, not just its carrier recombination lifetime. Time-resolved electroluminescence (TREL), which can characterize the luminescence decay of an LED under electrical injection to simulate real-world conditions when used in practical applications, is required. Both TRPL and TREL have been carried out on a semipolar LED and a standard c-plane LED (i.e., polar LED) both in the green spectral region for a comparison study. The (11-22) green semipolar LED exhibits much faster differential carrier lifetimes than the c-plane LED. In addition to a fast exponential component and a slow exponential component of 0.40 and 1.2 ns, respectively, which are similar to those obtained by TRPL, a third lifetime of 8.3 ns due to transport-related effects has been obtained from TREL, which has been confirmed by capacitance measurements. It has been found that the overall carrier lifetime of a c-plane LED is mainly limited by RC effects due to a junction capacitance, while it is not the case for a semipolar LED due to intrinsically reduced polarization, demonstrating the major advantages of using a semipolar LED for VLC.
时间分辨光致发光(TRPL)常用于研究半导体光电器件的激子动力学,比如III族氮化物发光二极管(LED)的载流子复合寿命。然而,对于任何需要电注入条件下LED的实际应用而言,由于未考虑载流子输运效应,TRPL存在内在局限性。对于用于可见光通信(VLC)的III族氮化物LED来说,这成为一个严峻问题,因为VLC的调制带宽由LED的整体载流子寿命决定,而不仅仅取决于其载流子复合寿命。因此需要时间分辨电致发光(TREL),它能够在电注入条件下表征LED的发光衰减情况,从而在实际应用中模拟真实条件。为了进行比较研究,在绿色光谱区域对一个半极性LED和一个标准c面LED(即极性LED)都开展了TRPL和TREL实验。(11-22)绿色半极性LED的差分载流子寿命比c面LED快得多。除了分别为0.40和1.2 ns的快速指数分量和慢速指数分量(这与TRPL获得的结果类似)之外,通过TREL还得到了由于输运相关效应导致的8.3 ns的第三寿命,这已通过电容测量得到证实。研究发现,c面LED的整体载流子寿命主要受结电容引起的RC效应限制,而半极性LED由于固有极化降低则并非如此,这证明了在VLC中使用半极性LED的主要优势。