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光响应超分子体系自组装的结构策略进展。

Advances in the Structural Strategies of the Self-Assembly of Photoresponsive Supramolecular Systems.

机构信息

Escuela de Ingeniería y Ciencias, Tecnologico de Monterrey, Campus Monterrey, Avenida Eugenio Garza Sada 2501, Monterrey 64849, Mexico.

Procesos de Polimerización, Centro de Investigación en Química Aplicada, Blvd. Enrique Reyna No. 140, Saltillo 25294, Mexico.

出版信息

Int J Mol Sci. 2022 Jul 20;23(14):7998. doi: 10.3390/ijms23147998.

DOI:10.3390/ijms23147998
PMID:35887350
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9317886/
Abstract

Photosensitive supramolecular systems have garnered attention due to their potential to catalyze highly specific tasks through structural changes triggered by a light stimulus. The tunability of their chemical structure and charge transfer properties provides opportunities for designing and developing smart materials for multidisciplinary applications. This review focuses on the approaches reported in the literature for tailoring properties of the photosensitive supramolecular systems, including MOFs, MOPs, and HOFs. We discuss relevant aspects regarding their chemical structure, action mechanisms, design principles, applications, and future perspectives.

摘要

光敏超分子体系因其在光刺激下通过结构变化来催化高度特异性任务的潜力而受到关注。它们的化学结构和电荷转移特性的可调谐性为设计和开发用于多学科应用的智能材料提供了机会。本综述重点介绍了文献中报道的用于调整光敏超分子体系性能的方法,包括 MOFs、MOPs 和 HOFs。我们讨论了与它们的化学结构、作用机制、设计原则、应用和未来展望相关的相关方面。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/733cbf8128eb/ijms-23-07998-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/edf47a8941c6/ijms-23-07998-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/ffb581074ae5/ijms-23-07998-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/1a42010558d5/ijms-23-07998-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/6f4d19c6e098/ijms-23-07998-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/733cbf8128eb/ijms-23-07998-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/edf47a8941c6/ijms-23-07998-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/ffb581074ae5/ijms-23-07998-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/1a42010558d5/ijms-23-07998-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/6f4d19c6e098/ijms-23-07998-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07e6/9317886/733cbf8128eb/ijms-23-07998-g004.jpg

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