Matykiewicz Danuta, Skórczewska Katarzyna
Faculty of Mechanical Engineering, Institute of Materials Technology, Poznan University of Technology, Piotrowo 3, 61-138 Poznan, Poland.
Faculty of Chemical Technology and Engineering, Bydgoszcz University of Science and Technology, Seminaryjna 3, 85-326 Bydgoszcz, Poland.
Materials (Basel). 2022 Jul 11;15(14):4824. doi: 10.3390/ma15144824.
The review article presents an analysis of the properties of epoxy and thermosetting resin composites containing eugenol derivatives. Moreover, eugenol properties were characterized using thermogravimeters (TGA) and Fourier-transform infrared spectroscopy (FTIR). The aim of this work was to determine the possibility of using eugenol derivatives in polymer composites based on thermoset resins, which can be used as eco-friendly high-performance materials. Eugenol has been successfully used in the production of epoxy composites as a component of coupling agents, epoxy monomers, flame retardants, curing agents, and modifiers. In addition, it reduced the negative impact of thermoset composites on the environment and, in some cases, enabled their biodegradation. Eugenol-based silane coupling agent improved the properties of natural filler epoxy composites. Moreover, eugenol flame retardant had a positive effect on the fire resistance of the epoxy resin. In turn, eugenol glycidyl ether (GE) was used as a diluent of epoxy ester resins during the vacuum infusion process of epoxy composites with the glass fiber. Eugenol-based epoxy resin was used to make composites with carbon fiber with enhanced thermomechanical properties. Likewise, resins such as bismaleimide resin, phthalonitrile resin, and palm oil-based resin have been used for the production of composites with eugenol derivatives.
这篇综述文章对含有丁香酚衍生物的环氧树脂和热固性树脂复合材料的性能进行了分析。此外，还使用热重分析仪（TGA）和傅里叶变换红外光谱仪（FTIR）对丁香酚的性能进行了表征。这项工作的目的是确定在基于热固性树脂的聚合物复合材料中使用丁香酚衍生物的可能性，这些复合材料可用作环保型高性能材料。丁香酚已成功用作环氧树脂复合材料生产中的偶联剂、环氧单体、阻燃剂、固化剂和改性剂的成分。此外，它减少了热固性复合材料对环境的负面影响，在某些情况下还能使其生物降解。基于丁香酚的硅烷偶联剂改善了天然填料环氧复合材料的性能。此外，丁香酚阻燃剂对环氧树脂的耐火性有积极影响。反过来，在玻璃纤维增强环氧复合材料的真空灌注过程中，丁香酚缩水甘油醚（GE）被用作环氧酯树脂的稀释剂。基于丁香酚的环氧树脂被用于制造具有增强热机械性能的碳纤维复合材料。同样，双马来酰亚胺树脂、邻苯二甲腈树脂和棕榈油基树脂等树脂也已用于生产含有丁香酚衍生物的复合材料。
