State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China.
Org Lett. 2022 Aug 5;24(30):5541-5545. doi: 10.1021/acs.orglett.2c02023. Epub 2022 Jul 27.
The skeleton of lucidumone was constructed through oxidative dearomatization/intramolecular Diels-Alder reaction, Cu-mediated remote C-H hydroxylation, allyl oxidation, acid-promoted dynamic kinetic resolution cyclization, and benzylic oxidation.
灵菌红素的骨架通过氧化去芳构化/分子内 Diels-Alder 反应、Cu 介导的远程 C-H 羟化、烯丙基氧化、酸促进的动态动力学拆分环化和苄基氧化构建。
