State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing, China.
National Laboratory of Solid State Microstructures, College of Engineering and Applied Sciences, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, China.
Nature. 2022 Aug;608(7921):69-73. doi: 10.1038/s41586-022-04942-4. Epub 2022 Aug 3.
Pressure-driven membranes is a widely used separation technology in a range of industries, such as water purification, bioprocessing, food processing and chemical production. Despite their numerous advantages, such as modular design and minimal footprint, inevitable membrane fouling is the key challenge in most practical applications. Fouling limits membrane performance by reducing permeate flux or increasing pressure requirements, which results in higher energetic operation and maintenance costs. Here we report a hydraulic-pressure-responsive membrane (PiezoMem) to transform pressure pulses into electroactive responses for in situ self-cleaning. A transient hydraulic pressure fluctuation across the membrane results in generation of current pulses and rapid voltage oscillations (peak, +5.0/-3.2 V) capable of foulant degradation and repulsion without the need for supplementary chemical cleaning agents, secondary waste disposal or further external stimuli. PiezoMem showed broad-spectrum antifouling action towards a range of membrane foulants, including organic molecules, oil droplets, proteins, bacteria and inorganic colloids, through reactive oxygen species (ROS) production and dielectrophoretic repulsion.
压力驱动膜是一种广泛应用于多个领域的分离技术,如水处理、生物加工、食品加工和化学生产。尽管它们具有模块化设计和占地面积小等诸多优点,但膜污染不可避免,这是大多数实际应用中的关键挑战。膜污染会降低渗透通量或增加压力要求,从而导致更高的能耗和运营维护成本。在这里,我们报告了一种液压压力响应膜(PiezoMem),它可以将压力脉冲转化为电活性响应,从而实现原位自清洁。膜两侧的瞬态液压波动会产生电流脉冲和快速电压振荡(峰值,+5.0/-3.2 V),能够降解和排斥污染物,而无需额外的化学清洁剂、二次废物处理或其他外部刺激。PiezoMem 通过活性氧(ROS)产生和介电泳排斥作用,对一系列膜污染物(包括有机分子、油滴、蛋白质、细菌和无机胶体)表现出广谱的抗污染作用。