"Nanoreactors" for Boosting Gas Hydrate Formation toward Energy Storage Applications.

Hydrogen and methane can be molecularly incorporated in ice-like water structures up to mass fractions of 4.3% and 13.3%, respectively. The resulting solid structures, called gas hydrates, offer great potential for the efficient storage of hydrogen and natural gas. However, slow gas encapsulation by bulk water hinders this application. Porous structures have been shown to effectively promote gas hydrate formation and are a potential enabler for the development of hydrate-based gas storage technologies. Here, we offer an insightful perspective on using porous structures as nanoreactors for achieving fast gas hydrate formation for gas storage applications. We critically discuss and elucidate the working mechanisms of nanoreactors and identify the criteria for efficient nanoreactors. Based on the concepts founded, we propose a theoretical framework for designing next-generation porous materials for delivering better promoting effects on gas hydrate formation.