Suppr超能文献

利用磁生物炭载体负载的芹菜叶提取物合成 Ag 纳米粒子作为还原反应的催化剂。

Synthesis of Ag nanoparticles by Celery leaves extract supported on magnetic biochar substrate, as a catalyst for the reduction reactions.

机构信息

Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, Vanak, POBox 1993891176, Tehran, Iran.

出版信息

Sci Rep. 2022 Aug 11;12(1):13678. doi: 10.1038/s41598-022-18131-w.

Abstract

Green synthesis of a noble metal such as Ag nanoparticles is an enormously developed research area. In this study, a biochar/FeO-Ag magnetic nanocatalyst was produced via a green path by using Celery stalk as a carbon-based substrate and Celery leaf extract as reducing and stabilizing agents to construct Ag nanoparticles. The synthesized nanocatalyst was determined using various techniques, such as UV-Vis spectroscopy, FT-IR spectroscopy, XRD (X-ray diffraction), SEM/EDX spectroscopy (scanning electron microscopy/energy-dispersive X-ray), TEM (transmission electron microscopy), and VSM (vibrating sample magnetometer). To survey the catalytic action of the biochar/FeO-Ag nanocatalyst, it was used in the reduction reaction of disparate nitroaromatics, aldehydes, and ketones. This catalyst has demonstrated good characteristics in terms of the amount, reusability, recoverability, activity, and structural integrity of the catalyst during the reaction. In addition, biochar/FeO-Ag could be detached magnetically and recycled multiple times without significantly reducing its catalytic performance.

摘要

绿色合成如 Ag 纳米粒子等贵金属是一个得到极大发展的研究领域。在这项研究中,通过使用芹菜茎作为碳基底和芹菜叶提取物作为还原剂和稳定剂来构建 Ag 纳米粒子,通过绿色途径制备了生物炭/FeO-Ag 磁性纳米催化剂。使用各种技术,如 UV-Vis 光谱、FT-IR 光谱、XRD(X 射线衍射)、SEM/EDX 光谱(扫描电子显微镜/能量分散 X 射线)、TEM(透射电子显微镜)和 VSM(振动样品磁强计)来确定所合成的纳米催化剂。为了考察生物炭/FeO-Ag 纳米催化剂的催化作用,它被用于不同硝基芳烃、醛和酮的还原反应。该催化剂在反应过程中表现出良好的特性,包括催化剂的用量、可重复使用性、可回收性、活性和结构完整性。此外,生物炭/FeO-Ag 可以通过磁性分离并多次回收,而不会显著降低其催化性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d8f9/9372062/42f1784085ee/41598_2022_18131_Fig1_HTML.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验