Li Xiaotong, Liang Huajian, Liu Xinlong, Zhang Yufei, Liu Zili, Fan Haosen
College of Materials Science and Metallurgy Engineering, Guizhou University, Guiyang, 550025, China.
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, China.
Chem Rec. 2022 Oct;22(10):e202200105. doi: 10.1002/tcr.202200105. Epub 2022 Aug 12.
Zeolite imidazolate frameworks (ZIFs), as a typical class of metal-organic frameworks (MOFs), have attracted a great deal of attention in the field of energy storage and conversation due to their chemical structure stability, facile synthesis and environmental friendliness. Among of ZIFs family, the zinc-based imidazolate framework (ZIF-8) and cobalt-based imidazolate framework (ZIF-67) have considered as promising ZIFs materials, which attributed to their tunable porosity, stable structure, and desirable electrical conductivity. To date, various ZIF-8 and ZIF67 derived materials, including carbon materials, metal oxides, sulfides, selenides, carbides and phosphides, have been successfully synthesized using ZIFs as templates and evaluated as promising electrode materials for secondary batteries and electrocatalysis. This review provides an effective guide for the comprehension of the performance optimization and application prospects of ZIFs derivatives, specifically focusing on the optimization of structure and their application in secondary batteries and electrocatalysis. In detail, we present recent advances in the improvement of electrochemical performance of ZIF-8, ZIF-67 and ZIF-8@ZIF-67 derived nanomaterials and their hybrids, including carbon materials, metal oxides, carbides, oxides, sulfides, selenides, and phosphides for high-performance secondary batteries and electrocatalysis.
沸石咪唑酯骨架材料（ZIFs）作为一类典型的金属有机骨架材料（MOFs），因其化学结构稳定性、合成简便性和环境友好性，在能量存储与转换领域备受关注。在ZIFs家族中，锌基金属咪唑酯骨架材料（ZIF-8）和钴基金属咪唑酯骨架材料（ZIF-67）被认为是很有前景的ZIFs材料，这归因于它们可调节的孔隙率、稳定的结构以及理想的导电性。迄今为止，已成功合成了各种由ZIF-8和ZIF-67衍生的材料，包括碳材料、金属氧化物、硫化物、硒化物、碳化物和磷化物，并将其评估为用于二次电池和电催化的有前景的电极材料。本综述为理解ZIFs衍生物的性能优化和应用前景提供了有效指导，特别关注结构优化及其在二次电池和电催化中的应用。详细地说，我们介绍了在改善ZIF-8、ZIF-67和ZIF-8@ZIF-67衍生的纳米材料及其杂化物（包括用于高性能二次电池和电催化的碳材料、金属氧化物、碳化物、氧化物、硫化物、硒化物和磷化物）的电化学性能方面的最新进展。
