阴离子辅助的脒基交换和复分解反应。
Anion-assisted amidinium exchange and metathesis.
机构信息
Institute of Organic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
出版信息
Chem Commun (Camb). 2022 Sep 13;58(73):10178-10181. doi: 10.1039/d2cc03425e.
Abstract
Dynamic covalent chemistry has become an invaluable tool for the design and preparation of adaptable yet robust molecular systems. Herein we explore the scope of a largely overlooked dynamic covalent reaction - amidinium exchange - and report on conditions that allow formal amidinium metathesis reactions.
摘要
动态共价化学已成为设计和制备适应性强且坚固的分子体系的不可或缺的工具。本文中，我们探索了一种很大程度上被忽视的动态共价反应——脒基交换的范围，并报告了可以进行形式脒基转移反应的条件。
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