Lockyer Selena J, Chiesa Alessandro, Brookfield Adam, Timco Grigore A, Whitehead George F S, McInnes Eric J L, Carretta Stefano, Winpenny Richard E P
Department of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Dipartimento di Scienze Matematiche, Fisiche e Informatiche, Università di Parma, I-43124 Parma, Italy.
J Am Chem Soc. 2022 Sep 7;144(35):16086-16092. doi: 10.1021/jacs.2c06384. Epub 2022 Aug 25.
We report a supramolecule that contains five spins of two different types and with, crucially, two different and predictable interaction energies between the spins. The supramolecule is characterized, and the interaction energies are demonstrated by electron paramagnetic resonance (EPR) spectroscopy. Based on the measured parameters, we propose experiments that would allow this designed supramolecule to be used to simulate quantum decoherence in maximally entangled Bell states that could be used in quantum teleportation.
我们报道了一种超分子,它包含两种不同类型的五个自旋,并且至关重要的是,自旋之间存在两种不同且可预测的相互作用能。对该超分子进行了表征,并通过电子顺磁共振(EPR)光谱证实了相互作用能。基于测量参数,我们提出了一些实验,这些实验将使这种设计的超分子能够用于模拟最大纠缠贝尔态中的量子退相干,而这种态可用于量子隐形传态。