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纳米层状双相高熵合金中与相体积分数相关的强化

Phase Volume Fraction-Dependent Strengthening in a Nano-Laminated Dual-Phase High-Entropy Alloy.

作者信息

Huang Cheng, Yao Yin, Chen Shaohua

机构信息

Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China.

Beijing Key Laboratory of Lightweight Multifunctional Composite Materials and Structures, Beijing Institute of Technology, Beijing 100081, China.

出版信息

ACS Omega. 2022 Aug 18;7(34):29675-29683. doi: 10.1021/acsomega.2c02027. eCollection 2022 Aug 30.

DOI:10.1021/acsomega.2c02027
PMID:36061647
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9435032/
Abstract

A recently synthesized FCC/HCP nano-laminated dual-phase (NLDP) CoCrFeMnNi high entropy alloy (HEA) exhibits excellent strength-ductility synergy. However, the underlying strengthening mechanisms of such a novel material is far from being understood. In this work, large-scale atomistic simulations of in-plane tension of the NLDP HEA are carried out in order to explore the HCP phase volume fraction-dependent strengthening. It is found that the dual-phase (DP) structure can significantly enhance the strength of the material, and the strength shows apparent phase volume fraction dependence. The yield stress increases monotonously with the increase of phase volume fraction, resulting from the increased inhibition effect of interphase boundary (IPB) on the nucleation of partial dislocations in the FCC lamella. There exists a critical phase volume fraction, where the flow stress is the largest. The mechanisms for the volume fraction-dependent flow stress include volume fraction-dependent phase strengthening effect, volume fraction-dependent IPB strengthening effect, and volume fraction-dependent IPB softening effect, that is, IPB migration and dislocation nucleation from the dislocation-IPB reaction sites. This work can provide a fundamental understanding for the physical mechanisms of strengthening effects in face-centered cubic HEAs with a nanoscale NLDP structure.

摘要

最近合成的面心立方/六方密排纳米层状双相(NLDP)CoCrFeMnNi高熵合金(HEA)表现出优异的强度-延展性协同效应。然而,这种新型材料潜在的强化机制仍远未被理解。在这项工作中,对NLDP高熵合金的面内拉伸进行了大规模原子模拟,以探索与六方密排相体积分数相关的强化作用。研究发现,双相(DP)结构可显著提高材料强度,且强度呈现明显的相体积分数依赖性。屈服应力随相体积分数的增加而单调增加,这是由于相界(IPB)对面心立方薄片中部分位错形核的抑制作用增强所致。存在一个临界相体积分数,此时流变应力最大。与体积分数相关的流变应力机制包括与体积分数相关的相强化效应、与体积分数相关的相界强化效应以及与体积分数相关的相界软化效应,即相界迁移和从位错-相界反应位点形核的位错。这项工作可为具有纳米级NLDP结构的面心立方高熵合金强化效应的物理机制提供基本认识。

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本文引用的文献

1
Plastic deformation and strengthening mechanism of FCC/HCP nano-laminated dual-phase CoCrFeMnNi high entropy alloy.面心立方/六方密排纳米层状双相CoCrFeMnNi高熵合金的塑性变形与强化机制
Nanotechnology. 2021 Oct 18;32(50). doi: 10.1088/1361-6528/ac2980.
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Hierarchical crack buffering triples ductility in eutectic herringbone high-entropy alloys.分级裂纹缓冲使共晶鱼骨状高熵合金具有延展性。
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双功能纳米沉淀物强化和延性化一种中熵合金。
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