Combination of Plasmon-Mediated Photochemistry and Seed-Mediated Methods for Synthesis of Bicomponent Nanocrystals.

Plasmon resonances of metal nanocrystals resulted from free electrons oscillating around nanocrystals, leading to a strong electromagnetic field around them. Because these oscillating electrons possess higher energy than the original ones, also known as hot electrons, these were widely used as photocatalysts for various reactions. Also, the strength and distribution of the electromagnetic field around the nanocrystals strongly depended on their morphology and excited irradiation, which led to the reaction environment around nanocrystals being controllable. Here, we integrated the seed-mediated and plasmon-mediated photochemistry methods for fabricating bimetallic and semiconductor-metal nanocrystals with controllable morphologies and compositions of the nanocrystals, resulting from the highly anisotropic reaction environment around the nanocrystals. The highly anisotropic reaction environment around the template nanocrystal was caused by the distribution of electromagnetic fields around it and its exposure area in the reaction solution. This new synthesis method should enable the fabrication of various multicomponent nanocrystals with desirable functions for potential applications, such as photocatalysts, chemical sensors, biosensors, biomedicines, etc.