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通过BiOClBr实现对生物顽固微生物的远程光催化根除——可见光驱动光催化的应用方面

Remote Photocatalytic Eradication of Biorecalcitrant Microorganisms via BiOClBr-The Applied Aspects of Visible Light-Driven Photocatalysis.

作者信息

Abbasi Razan, Gnayem Hani, Sasson Yoel

机构信息

Casali Center of Applied Chemistry, Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 9190401, Israel.

出版信息

ACS Omega. 2022 Aug 15;7(34):29625-29633. doi: 10.1021/acsomega.2c01502. eCollection 2022 Aug 30.

Abstract

Photocatalysis has an exceptional capacity to eliminate a wide range of harmful microorganisms and is proven to be superior over commonly used disinfection methods. A visible light-induced photocatalyst, the BiOClBr@gypsum hybrid composite, composed of microspheres (∼3 μm) molded with a gypsum composite as a honeycomb-shaped filter was proven to inactivate a large selection of bacteria including , and via remote photocatalysis. The chemical composition and morphology of the composite were unveiled with the help of scanning electron microscopy, transmission electron microscopy, N sorption, Fourier transform infrared spectroscopy, diffuse reflectance spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. After 6 h under ambient conditions, our system declined the number of viable bacteria by fourfold. A similar effect was observed at a low temperature, where we rapidly and completely diminished inside a refrigerator within 24 h of visible light illumination.

摘要

光催化具有卓越的能力来消除多种有害微生物,并且已被证明优于常用的消毒方法。一种可见光诱导的光催化剂,即BiOClBr@石膏杂化复合材料,由微球(约3μm)组成,这些微球由石膏复合材料模塑而成,呈蜂窝状过滤器,已被证明可通过远程光催化使大量细菌失活,包括大肠杆菌、金黄色葡萄球菌和枯草芽孢杆菌。借助扫描电子显微镜、透射电子显微镜、氮吸附、傅里叶变换红外光谱、漫反射光谱、X射线衍射和X射线光电子能谱揭示了该复合材料的化学成分和形态。在环境条件下6小时后,我们的系统使活菌数量减少了四倍。在低温下也观察到了类似的效果,在可见光照射24小时内,我们在冰箱内迅速且完全地减少了大肠杆菌的数量。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db68/9434757/1e3736b6afb2/ao2c01502_0002.jpg

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