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含铜和钯的水凝胶用于催化还原/降解有机污染物的最新进展。

Recent developments in hydrogels containing copper and palladium for the catalytic reduction/degradation of organic pollutants.

作者信息

Dadashi Jaber, Ghasemzadeh Mohammad Ali, Salavati-Niasari Masoud

机构信息

Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology Tehran Iran.

Department of Chemistry, Qom Branch, Islamic Azad University Qom Iran

出版信息

RSC Adv. 2022 Aug 18;12(36):23481-23502. doi: 10.1039/d2ra03418b. eCollection 2022 Aug 16.

Abstract

The elimination of toxic and hazardous contaminants from different environmental media has become a global challenge, causing researchers to focus on the treatment of pollutants. Accordingly, the elimination of inorganic and organic pollutants using sustainable, effective, and low-cost heterogeneous catalysts is considered as one of the most essential routes for this aim. Thus, many efforts have been devoted to the synthesis of novel compounds and improving their catalytic performance. Recently, palladium- and copper-based hydrogels have been used as catalysts for reduction, degradation, and decomposition reactions because they have significant features such as high mechanical strength, thermal stability, and high surface area. Herein, we summarize the progress achieved in this field, including the various methods for the synthesis of copper- and palladium-based hydrogel catalysts and their applications for environmental remediation. Moreover, palladium- and copper-based hydrogel catalysts, which have certain advantages, including high catalytic ability, reusability, easy work-up, and simple synthesis, are proposed as a new group of effective catalysts.

摘要

从不同环境介质中去除有毒有害污染物已成为一项全球性挑战,促使研究人员专注于污染物的处理。因此,使用可持续、有效且低成本的非均相催化剂去除无机和有机污染物被视为实现这一目标的最关键途径之一。为此,人们付出了诸多努力来合成新型化合物并提高其催化性能。最近,钯基和铜基水凝胶因其具有高机械强度、热稳定性和高比表面积等显著特性,已被用作还原、降解和分解反应的催化剂。在此,我们总结了该领域取得的进展,包括铜基和钯基水凝胶催化剂的各种合成方法及其在环境修复中的应用。此外,钯基和铜基水凝胶催化剂具有高催化活性、可重复使用性、后处理简便和合成简单等优点,被提议作为一类新型的有效催化剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f0e/9386442/27869e27bbdd/d2ra03418b-s1.jpg

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