Wazalwar Radhika, Sahu Megha, Raichur Ashok M
Department of Materials Engineering, Indian Institute of Science Bengaluru India
Nanoscale Adv. 2021 Mar 29;3(10):2741-2776. doi: 10.1039/d1na00050k. eCollection 2021 May 18.
High-performance epoxy composites find application in the aerospace industry. Although epoxy is a high-performance polymer, its fracture toughness is compromised due to its highly cross-linked nature. Nanomaterials such as carbon nanotubes (CNTs), graphene derivatives, and inorganic 2-dimensional (2D) nanomaterials are being explored to improve epoxy composites' mechanical properties. Graphene is one of the most popular 2D nano-reinforcing agents for epoxy composites. Following graphene discovery, the research community's attention was brought to various other few-atom thick 2D nanomaterials. Hence, apart from graphene, inorganic nanosheets such as transition metal dichalcogenides (TMDs), hexagonal boron nitride (hBN), , are also being studied as modifiers for enhancing the mechanical performance of epoxy composites. Graphene, TMDs and hBN are known to possess a high aspect ratio, high specific surface area and inherently high mechanical strength and stiffness, contributing to a stronger and tougher composite. Despite that, the challenges associated with these nanomaterials, such as dispersion issues, lack of standardization, underlying health hazards, , have hampered their commercialization. It has been long past a decade since the discovery of graphene, yet there are concerns regarding the lab to industry scale-up, and health and environmental hazards associated with nanomaterials for the fabrication of aerospace composites. This review offers a comprehensive literature survey and a perspective into the possible ways of bridging the gaps between the laboratory research and industrialization of 2D nanosheet-filled epoxy composites.
高性能环氧复合材料在航空航天工业中得到应用。尽管环氧树脂是一种高性能聚合物,但其高度交联的性质使其断裂韧性受到影响。人们正在探索使用碳纳米管(CNT)、石墨烯衍生物和无机二维(2D)纳米材料等纳米材料来改善环氧复合材料的机械性能。石墨烯是用于环氧复合材料的最受欢迎的二维纳米增强剂之一。随着石墨烯的发现,研究界的注意力转向了其他各种几原子厚的二维纳米材料。因此,除了石墨烯之外,诸如过渡金属二硫属化物(TMD)、六方氮化硼(hBN)等无机纳米片也正在作为增强环氧复合材料机械性能的改性剂进行研究。已知石墨烯、TMD和hBN具有高纵横比、高比表面积以及固有的高机械强度和刚度,有助于形成更强韧的复合材料。尽管如此,与这些纳米材料相关的挑战,如分散问题、缺乏标准化、潜在的健康危害等,阻碍了它们的商业化。自石墨烯发现以来已经过去十多年了,但对于从实验室规模扩大到工业规模以及与用于制造航空航天复合材料的纳米材料相关的健康和环境危害仍存在担忧。本综述提供了全面的文献调查,并对弥合二维纳米片填充环氧复合材料的实验室研究与工业化之间差距的可能方法进行了展望。