电化学和光谱电化学技术在共轭聚合物制备与表征中的作用：从聚苯胺到现代有机半导体

Ledwon Przemyslaw, Lapkowski Mieczyslaw

Department of Physical Chemistry and Technology of Polymers, Faculty of Chemistry, Silesian University of Technology, Strzody 9, 44-100 Gliwice, Poland.

Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22B, 44-100 Gliwice, Poland.

Polymers (Basel). 2022 Oct 5;14(19):4173. doi: 10.3390/polym14194173.

This review article presents different electrochemical and spectroelectrochemical techniques used to investigate conjugated polymers. The development of this research area is presented from an over 40-year perspective-the period of research carried out by Professor Mieczyslaw Lapkowski. Initial research involved polymers derived from simple aromatic compounds, such as polyaniline. Since then, scientific advances in the field of conductive polymers have led to the development of so-called organic electronics. Electrochemical and spectroelectrochemical methods have a great influence in the development of organic semiconductors. Their potential for explaining many phenomena is discussed and the most relevant examples are provided.

这篇综述文章介绍了用于研究共轭聚合物的不同电化学和光谱电化学技术。本文从40多年的视角呈现了这一研究领域的发展历程——这也是米切斯瓦夫·拉普科夫斯基教授开展研究的时期。最初的研究涉及由简单芳香族化合物衍生而来的聚合物，比如聚苯胺。从那时起，导电聚合物领域的科学进展推动了所谓有机电子学的发展。电化学和光谱电化学方法对有机半导体的发展产生了重大影响。文中讨论了它们解释诸多现象的潜力，并给出了最具相关性的实例。