Electrochemically Produced Copolymers of Pyrrole and Its Derivatives: A Plentitude of Material Properties Using "Simple" Heterocyclic Co-Monomers.

Polypyrrole is a classical, well-known conjugated polymer that is produced from a simple heterocyclic system. Numerous pyrrole derivatives exhibit biological activity, and the repeat unit is a common building block present in the chemical structure of many polymeric materials, finding wide application, primarily in optoelectronics and sensing. In this work, we focus on the variety of copolymers and their material properties that can be produced electrochemically, even though all these systems are obtained from mixtures of the "simple" pyrrole monomer and its derivatives with different conjugated and non-conjugated species.