Chemical Engineering Department, Mersin University, Çiftlikköy Campus, 33110Mersin, Turkey.
ACS Appl Bio Mater. 2022 Nov 21;5(11):5465-5476. doi: 10.1021/acsabm.2c00782. Epub 2022 Oct 25.
It has been well known that metallic nanoparticles with striking properties possess wide application prospects in the processes of colorimetric detection, catalysis, disease diagnosis and treatment, energy, wastewater treatment, remediation, and antibacterial activity in recent years. Herein, iron-based nanoparticles (FeNPs), metallic nanoparticles, were synthesized via a facile chemical reduction method using a hyperaccumulator plant. Also, their use in antibacterial activity applications and colorimetric ascorbic acid (AA) detection was investigated. It was observed that FeNPs presented high antibacterial potency against Gram-positive bacteria of and and also Gram-negative bacteria of , , , and . Moreover, it was found that FeNPs exhibited superior peroxidase-like activity to catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) to produce a blue color product, oxidized TMB (oxTMB), in the presence of HO. The colorimetric AA detection could be carried out by making the solution color lighter owing to the antioxidant property of AA. The quantitative detection of AA could be performed simply, selectively, and sensitively with FeNPs with a detection limit (LOD) of 0.5462 μM in a linear range of 30-200 μM.
近年来,具有显著特性的金属纳米粒子在比色检测、催化、疾病诊断和治疗、能源、废水处理、修复和抗菌活性等过程中具有广泛的应用前景。本文采用一种简单的化学还原法,利用超富集植物合成了铁基纳米粒子(FeNPs),即金属纳米粒子,并研究了其在抗菌活性应用和比色检测抗坏血酸(AA)方面的应用。结果表明,FeNPs 对革兰氏阳性菌 和 以及革兰氏阴性菌 、 、 、 具有很高的抗菌效力。此外,研究发现 FeNPs 具有优异的过氧化物酶样活性,可在 HO 存在下催化 3,3',5,5'-四甲基联苯胺(TMB)氧化生成蓝色产物氧化 TMB(oxTMB)。由于 AA 的抗氧化性质,可以通过使溶液颜色变浅来进行比色 AA 检测。FeNPs 可用于简单、选择性和灵敏地定量检测 AA,其检测限(LOD)为 0.5462 μM,线性范围为 30-200 μM。