Pu Tiancheng, Zhang Wenhao, Zhu Minghui
State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China.
Angew Chem Int Ed Engl. 2023 Jan 23;62(4):e202212278. doi: 10.1002/anie.202212278. Epub 2022 Dec 7.
Strong metal-support interactions (SMSI) represent a classic yet fast-growing area in catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of metal nanoparticles (NPs) with the support material that significantly impacts the catalytic performance through regulation of the interfacial interactions. Engineering SMSI provides a promising approach to steer catalytic performance in various chemical processes, which serves as an effective tool to tackle energy and environmental challenges. Our Minireview covers characterization, theory, catalytic activity, dependence on the catalytic structure and inducing environment of SMSI phenomena. By providing an overview and outlook on the cutting-edge techniques in this multidisciplinary research field, we not only want to provide insights into the further exploitation of SMSI in catalysis, but we also hope to inspire rational designs and characterization in the broad field of material science and physical chemistry.
强金属-载体相互作用（SMSI）是催化研究领域一个经典且快速发展的领域。SMSI现象导致金属纳米颗粒（NPs）被载体材料包裹并稳定，通过调节界面相互作用对催化性能产生显著影响。设计SMSI为控制各种化学过程中的催化性能提供了一种有前景的方法，是应对能源和环境挑战的有效工具。我们的小型综述涵盖了SMSI现象的表征、理论、催化活性、对催化结构的依赖性以及诱导环境。通过对这一多学科研究领域前沿技术的概述和展望，我们不仅希望为进一步开发SMSI在催化中的应用提供见解，还希望在材料科学和物理化学的广泛领域激发合理的设计和表征。
