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不饱和化合物的直接硒磺酰化反应:综述

Direct selenosulfonylation of unsaturated compounds: a review.

作者信息

Abdtawfeeq Tarik Hafdhi, Mahmood Evan Abdulkareem, Azimi Seyedeh Bahareh, Kadhim Mustafa M, Kareem Rzgar Tawfeeq, Charati Faramarz Rostami, Vessally Esmail

机构信息

Medical Laboratory Techniques College, Al-Farahidi University Baghdad Iraq.

Medical Laboratory Sciences Department, College of Health Sciences, University of Human Development Sulaymaniyah Iraq.

出版信息

RSC Adv. 2022 Oct 26;12(47):30564-30576. doi: 10.1039/d2ra04128f. eCollection 2022 Oct 24.

DOI:10.1039/d2ra04128f
PMID:36337948
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9597415/
Abstract

In this review, we have discussed recent developments on the direct selenosulfonylation of unsaturated compounds which lead to the formation of two new carbon-sulfur and carbon-selenium bonds in a single operation. The reactions were classified based on the type of starting unsaturated compound and product. Thus, the review is divided into three major sections. The first describes the current literature on selenosulfonylation of alkenes. The second section covers the available literature on selenosulfonylation of alkynes. The third focuses exclusively on selenosulfonylation of allenes.

摘要

在本综述中,我们讨论了不饱和化合物直接硒磺酰化反应的最新进展,该反应可在一步操作中形成两个新的碳 - 硫键和碳 - 硒键。这些反应根据起始不饱和化合物和产物的类型进行分类。因此,本综述分为三个主要部分。第一部分描述了关于烯烃硒磺酰化反应的当前文献。第二部分涵盖了关于炔烃硒磺酰化反应的现有文献。第三部分专门聚焦于丙二烯的硒磺酰化反应。

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Rh(iii)-catalyzed synthesis of dibenzo[,]pyran-6-ones from aryl ketone -acetyl oximes and quinones C-H activation and C-C bond cleavage.铑(III)催化由芳基酮 - 乙酰肟和醌合成二苯并[,]吡喃 - 6 - 酮:C-H活化和C-C键断裂
RSC Adv. 2022 May 12;12(23):14435-14438. doi: 10.1039/d2ra02074b.
2
4-(3-Alkyl/benzyl-guanidino)benzenesulfonamides as selective carbonic anhydrase VII inhibitors.4-(3-烷基/苄基胍基)苯磺酰胺类作为选择性碳酸酐酶 VII 抑制剂。
J Enzyme Inhib Med Chem. 2022 Dec;37(1):1568-1576. doi: 10.1080/14756366.2022.2080816.
3
Decarboxylative cross-coupling reactions for P(O)-C bond formation.
用于形成P(O)-C键的脱羧交叉偶联反应。
RSC Adv. 2018 Jul 24;8(46):26383-26398. doi: 10.1039/c8ra04557g. eCollection 2018 Jul 19.
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Recent advances in sulfur-nitrogen bond formation cross-dehydrogenative coupling reactions.硫氮键形成交叉脱氢偶联反应的最新进展。
RSC Adv. 2018 May 21;8(33):18456-18469. doi: 10.1039/c8ra00356d. eCollection 2018 May 17.
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Direct sulfonamidation of (hetero)aromatic C-H bonds with sulfonyl azides: a novel and efficient route to -(hetero)aryl sulfonamides.(杂)芳族C-H键与磺酰叠氮的直接磺酰胺化:一种合成(杂)芳基磺酰胺的新颖高效方法。
RSC Adv. 2020 Oct 8;10(61):37299-37313. doi: 10.1039/d0ra04255b. eCollection 2020 Oct 7.
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Design, synthesis and biological evaluation of new 2-aminothiazole scaffolds as phosphodiesterase type 5 regulators and COX-1/COX-2 inhibitors.新型2-氨基噻唑支架作为5型磷酸二酯酶调节剂和COX-1/COX-2抑制剂的设计、合成及生物学评价
RSC Adv. 2020 Aug 11;10(50):29723-29736. doi: 10.1039/d0ra05561a. eCollection 2020 Aug 10.
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RSC Adv. 2019 Mar 18;9(16):8964-8976. doi: 10.1039/c9ra00929a. eCollection 2019 Mar 15.
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