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基于GAFASnI-1%EDAI薄膜的26%效率且稳健的倒置平面钙钛矿太阳能电池的模拟与研究

Simulation and Investigation of 26% Efficient and Robust Inverted Planar Perovskite Solar Cells Based on GAFASnI-1%EDAI Films.

作者信息

Sabbah Hussein, Arayro Jack, Mezher Rabih

机构信息

College of Engineering and Technology, American University of the Middle East, Eqaila 54200, Kuwait.

出版信息

Nanomaterials (Basel). 2022 Nov 3;12(21):3885. doi: 10.3390/nano12213885.

DOI:10.3390/nano12213885
PMID:36364661
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9657588/
Abstract

A hybrid tin-based perovskite solar cell with -- inverted structure is modeled and simulated using SCAPS. The inverted structure is composed of PEDOT:PSS (as hole transport layer-HTL)/GA0.2FA0.78SnI3-1% EDAI2 (as perovskite absorber layer)/C60-fullerene (as electron transport layer-ETL). Previous experimental studies showed that unlike conventional tin-based perovskite solar cells (PSC), the present hybrid tin-based PSC passes all harsh standard tests and generates a power conversion efficiency of only 8.3%. Despite the high stability that this material exhibits, emphasis on enhancing its power conversion efficiency (PCE) is crucial. To that end, various ETL and HTL materials have been rigorously investigated. The impact of energy level alignment between HTL/absorber and absorber/ETL interfaces have been elucidated. Moreover, the thickness and the doping concentration of all the previously mentioned layers have been varied to inspect their effect on the photovoltaic performance of the PSC. The optimized structure with CuI (copper iodide) as HTL and ZnOS (zinc oxysulphide) as ETL scored a PCE of 26%, which is more than three times greater than the efficiency of the initial structure. The current numerical simulation on GA0.2FA0.78SnI3-1% EDAI2 could greatly increase its chance for commercial development.

摘要

采用SCAPS对具有倒置结构的混合锡基钙钛矿太阳能电池进行了建模和模拟。该倒置结构由PEDOT:PSS（作为空穴传输层-HTL）/GA0.2FA0.78SnI3-1% EDAI2（作为钙钛矿吸收层）/C60-富勒烯（作为电子传输层-ETL）组成。先前的实验研究表明，与传统的锡基钙钛矿太阳能电池（PSC）不同，目前的混合锡基PSC通过了所有严格的标准测试，但其功率转换效率仅为8.3%。尽管这种材料具有很高的稳定性，但提高其功率转换效率（PCE）仍然至关重要。为此，对各种ETL和HTL材料进行了严格研究。阐明了HTL/吸收层和吸收层/ETL界面之间能级对齐的影响。此外，还改变了上述所有层的厚度和掺杂浓度，以考察它们对PSC光伏性能的影响。以碘化铜（CuI）作为HTL和硫氧化锌（ZnOS）作为ETL的优化结构的PCE达到了26%，这比初始结构的效率高出三倍多。目前对GA0.2FA0.78SnI3-1% EDAI2的数值模拟可以大大增加其商业开发的机会。

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