Adekoya Gbolahan Joseph, Adekoya Oluwasegun Chijioke, Sadiku Rotimi Emmanuel, Hamam Yskandar, Ray Suprakas Sinha
Institute of Nanoengineering Research (INER) and Department of Chemical, Metallurgical and Materials Engineering, Faculty of Engineering and the Built Environment, Tshwane University of Technology, Pretoria 0001, South Africa.
Centre for Nanostructures and Advanced Materials, DSI-CSIR Nanotechnology Innovation Centre, Council for Scientific and Industrial Research, CSIR, Pretoria 0001, South Africa.
ACS Omega. 2022 Oct 25;7(44):39498-39519. doi: 10.1021/acsomega.2c02706. eCollection 2022 Nov 8.
The atomically thick two-dimensional (2D) materials are at the forefront of revolutionary technologies for energy storage devices. Due to their fascinating physical and chemical features, these materials have gotten a lot of attention. They are particularly appealing for a wide range of applications, including electrochemical storage systems, due to their simplicity of property tuning. The MXene is a type of 2D material that is widely recognized for its exceptional electrochemical characteristics. The use of these materials in conjunction with conducting polymers, notably polypyrrole (PPy), has opened new possibilities for lightweight, flexible, and portable electrodes. Therefore, herein we report a comprehensive review of recent achievements in the production of MXene/PPy nanocomposites. The structural-property relationship of this class of nanocomposites was taken into consideration with an elaborate discussion of the various characterizations employed. As a result, this research gives a narrative explanation of how PPy interacts with distinct MXenes to produce desirable high-performance nanocomposites. The effects of MXene incorporation on the thermal, electrical, and electrochemical characteristics of the resultant nanocomposites were discussed. Finally, it is critically reviewed and presented as an advanced composite material in electrochemical storage devices, energy conversion, electrochemical sensors, and electromagnetic interference shielding.
原子级厚度的二维(2D)材料处于储能设备革命技术的前沿。由于其迷人的物理和化学特性,这些材料受到了广泛关注。由于其性质调节的简便性,它们在包括电化学存储系统在内的广泛应用中特别有吸引力。MXene是一种二维材料,因其卓越的电化学特性而广受认可。将这些材料与导电聚合物,特别是聚吡咯(PPy)结合使用,为轻质、柔性和便携式电极开辟了新的可能性。因此,本文我们对MXene/PPy纳米复合材料制备方面的最新成果进行了全面综述。考虑了这类纳米复合材料的结构-性能关系,并详细讨论了所采用的各种表征方法。结果,本研究对PPy如何与不同的MXene相互作用以制备理想的高性能纳米复合材料进行了叙述性解释。讨论了MXene掺入对所得纳米复合材料的热、电和电化学特性的影响。最后,对其作为电化学存储设备、能量转换、电化学传感器和电磁干扰屏蔽中的先进复合材料进行了批判性综述和介绍。