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菁染料 J-聚集的理论模型、制备、表征及应用:综述。

Theoretical Models, Preparation, Characterization and Applications of Cyanine J-Aggregates: A Minireview.

机构信息

Department of Physics, Faculty of Natural Science, Ariel University, Ariel, 40700, Israel.

出版信息

ChemistryOpen. 2022 Nov;11(11):e202200103. doi: 10.1002/open.202200103.

DOI:10.1002/open.202200103
PMID:36423932
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9691386/
Abstract

Cyanines are one of the few kinds of molecules whose absorbance and emission can be shifted in a broad spectral range from the ultraviolet to the near infrared. They can easily transform into J-aggregates with narrow absorption and emission peaks, along with a redshift in their spectra. This mini-review presents cyanine dyes and their J-aggregates and discusses their structure and spectral properties that illustrate their specificities. We summarize the theoretical and experimental state of the art on cyanine J-aggregates and their applications, also laying the groundwork for cyanine J-aggregates synthesis and characterization methods.

摘要

菁染料是为数不多的能在从紫外到近红外的宽光谱范围内实现吸收和发射移动的分子之一。它们很容易形成具有窄吸收和发射峰以及光谱红移的 J-聚集体。这篇迷你综述介绍了菁染料及其 J-聚集体,并讨论了它们的结构和光谱性质,说明了它们的特异性。我们总结了菁 J-聚集体及其应用的理论和实验现状,也为菁 J-聚集体的合成和表征方法奠定了基础。

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Acc Chem Res. 2021 Feb 2;54(3):642-653. doi: 10.1021/acs.accounts.0c00590. Epub 2020 Dec 8.
2
Shortwave infrared polymethine fluorophores matched to excitation lasers enable non-invasive, multicolour in vivo imaging in real time.短波近红外多甲川荧光团与激发激光匹配,可实现实时非侵入式多色活体成像。
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3
Thermodynamic Control over Molecular Aggregate Assembly Enables Tunable Excitonic Properties across the Visible and Near-Infrared.
近红外二区J-聚集三碳菁的可调荧光发射
J Phys Chem B. 2023 Sep 21;127(37):7988-7995. doi: 10.1021/acs.jpcb.3c04554. Epub 2023 Sep 8.
通过热力学控制分子聚集体组装实现可见光和近红外范围内可调谐的激子特性。
J Phys Chem Lett. 2020 Oct 1;11(19):8026-8033. doi: 10.1021/acs.jpclett.0c02204. Epub 2020 Sep 11.
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NIR-emitting squaraine J-aggregate nanosheets.发射近红外光的方酸 J-聚集体纳米片。
Chem Commun (Camb). 2020 Aug 25;56(68):9878-9881. doi: 10.1039/d0cc03686b.
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J Am Chem Soc. 2019 Dec 11;141(49):19221-19225. doi: 10.1021/jacs.9b10043. Epub 2019 Nov 27.
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