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馒头与蛋壳界面黏附的分析。

Analysis of Adhesion at the Interface of Steamed Bread and Eggshell.

机构信息

Key Laboratory of Education Ministry for Modern Design and Rotor-Bearing System, Xi'an Jiaotong University, Xi'an 710049, China.

出版信息

Molecules. 2022 Nov 24;27(23):8179. doi: 10.3390/molecules27238179.

Abstract

The adhesion phenomenon of polymers occurs in nature and in human activity. In the present paper, an adhesion system of steamed bread and eggshell was observed in formation when steamed bread and eggshells were placed in close contact and cooled slightly in the ambient air. The adhesion phenomena and mechanism of the adhesion interface between the steamed bread and eggshell were investigated and systematically discussed. Strong-bond interfaces were observed by scanning electron microscope (SEM). The formation process and mechanism of the strong-bond adhesion were also analyzed molecular dynamics simulation technology, and the results are discussed. The simulation analyses showed that the starch molecules at the calcite (104) crystal face were diffused in a water vapor environment, and the formation and solidification of multiple hydrogen bonds in the starch chain and oxygen atoms in the calcium carbonate were observed in detail during cooling. The diffusion rate of hydrogen atoms in hydroxyl groups on the calcite surface decreased gradually with the decrease of the cooling temperature of the steamed bread's upper surface. The strong adhesion of the steamed bread and eggshell is attributed to the synthetic effect of the absorption, diffusion, surface chemistry, and the formation of multiple hydrogen bonds between the starch from the steamed bread and the calcium carbonate crystals in eggshell. The interesting findings are helpful for the design of strong bonds, and provide an idea for new environmentally friendly adhesive materials.

摘要

聚合物的粘附现象存在于自然界和人类活动中。本文研究了馒头和蛋壳在环境空气中轻微接触和冷却时形成的粘附体系。研究并系统讨论了馒头和蛋壳之间粘附界面的粘附现象和机制。利用扫描电子显微镜(SEM)观察到强键界面。还利用分子动力学模拟技术分析了强键粘附的形成过程和机制,并对结果进行了讨论。模拟分析表明,在水蒸气环境中,方解石(104)晶面上的淀粉分子发生扩散,在冷却过程中详细观察到淀粉链中的多个氢键和碳酸钙中的氧原子的形成和固化。随着馒头表面冷却温度的降低,方解石表面羟基上氢原子的扩散速率逐渐降低。馒头和蛋壳的强粘附归因于馒头中的淀粉与蛋壳中碳酸钙晶体之间的吸收、扩散、表面化学和多个氢键形成的综合效应。这一有趣的发现有助于设计强键,并为新型环保胶粘剂材料提供了思路。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce13/9737473/730f01d9eb71/molecules-27-08179-g001a.jpg

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