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合成及表征负载双金属 Pd 基纳米粒子的活性炭及其传感器和抗菌性能研究。

Synthesis and characterization of activated carbon supported bimetallic Pd based nanoparticles and their sensor and antibacterial investigation.

机构信息

Department of Botany and Microbiology, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia.

School of Resources and Environment, University of Electronic Science and Technology of China, 611731, Xiyuan Ave, Chengdu, PR China; Department of Sustainable Engineering, Saveetha School of Engineering, SIMATS, Chennai, 602105, India; Department of Chemical Sciences, University of Johannesburg, Doornfontein Campus, 2028 Johannesburg, 17011, South Africa.

出版信息

Environ Res. 2023 Mar 15;221:115287. doi: 10.1016/j.envres.2023.115287. Epub 2023 Jan 11.

Abstract

Activated carbon (AC) supported palladium cobalt bimetallic nanoparticles (PdCo@AC NPs) were obtained by green synthesis method using Cinnamomum verum (C. Verum) extract. The obtained NPs were characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-Ray Crystallography (XRD), Transmission Electron Microscope (TEM) and Ultraviolet Visible (UV-VIS) spectroscopy, and the functional groups and morphology of the nanoparticle were elucidated. The resulting particle size was found to be 2.467 nm. NPs were evaluated using Cyclic Voltammetry (CV), Scan Rate (SR), and Differential Pulse Voltammetry (DPV) techniques for potential dopamine sensors application. According to the obtained DPV results, Limit of Detection (LOD) and Limit of Quantitation (LOQ) values are found to be 5.68 pM and 17.21 pM, respectively. It was also observed that AC supported PdCo nanoparticles obtained from C. verum extract sensed dopamine quite well. Besides, to examine the antibacterial properties of NPs, antibacterial analyzes were performed with Escherichia coli (E. Coli) and Staphylococcus aureus (S. Aureus). It was observed that it showed good antibacterial properties against gram positive (S. aureus) and gram negative (E. coli) bacteria. The study gave important results in terms of the synthesis of bimetallic NPs using the green synthesis method and their usability in different areas. With this study, it was observed that a good antibacterial dopamine sensor were obtained with the successful biogenic synthesis of AC supported PdCo bimetallic NPs.

摘要

采用绿色合成法,以肉桂(C. Verum)提取物合成了负载钯钴双金属纳米粒子(PdCo@AC NPs)的活性炭(AC)。采用傅里叶变换红外光谱(FTIR)、X 射线晶体学(XRD)、透射电子显微镜(TEM)和紫外可见(UV-VIS)光谱对所得纳米粒子进行了表征,并对纳米粒子的官能团和形态进行了阐述。结果表明,所得粒子的尺寸为 2.467nm。采用循环伏安法(CV)、扫描速率(SR)和差分脉冲伏安法(DPV)技术对纳米粒子进行评价,以评估其作为潜在多巴胺传感器的应用。根据所得 DPV 结果,发现检测限(LOD)和定量限(LOQ)值分别为 5.68 pM 和 17.21 pM。还观察到,从肉桂提取物中获得的负载 PdCo 纳米粒子的活性炭对多巴胺的检测效果很好。此外,为了研究纳米粒子的抗菌性能,采用大肠杆菌(E. coli)和金黄色葡萄球菌(S. Aureus)进行了抗菌分析。结果表明,它对革兰氏阳性(S. aureus)和革兰氏阴性(E. coli)细菌均表现出良好的抗菌性能。该研究在使用绿色合成法合成双金属纳米粒子及其在不同领域的可用性方面取得了重要成果。通过这项研究,观察到通过成功的生物合成负载 PdCo 双金属纳米粒子的活性炭,获得了一种良好的抗菌多巴胺传感器。

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