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通过喷墨打印制备均匀的聚二甲基硅氧烷阵列。

Development of Uniform Polydimethylsiloxane Arrays through Inkjet Printing.

作者信息

Tu Ning, Lo Jeffery C C, Lee S W Ricky

机构信息

Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Hong Kong SAR, China.

Foshan Research Institute for Smart Manufacturing, The Hong Kong University of Science and Technology, Hong Kong SAR, China.

出版信息

Polymers (Basel). 2023 Jan 16;15(2):462. doi: 10.3390/polym15020462.

Abstract

The inkjet printing method is a promising method to deposit polymer and functional nanoparticles at the microscale. It can be applied in the fabrication of multicolor polymer light emitting diodes (polyLEDs), polymer base electronics, multicolor color conversion layers, and quantum dot light emitting diodes (QLEDs). One of the main challenges is to print high-resolution polymer dots from dilute polymer solution. In addition, the quality of printed multicolor polyLEDs, QLEDs and multicolor color conversion layers is currently limited by non-uniformity of the printed dots. In this paper, polydimethylsiloxane (PDMS) is selected as the functional polymer, due to its high transparency, good reflective index value, inflammable and flexible properties. The optimal ink to form a uniform PDMS dot array is presented in this paper. Both the solvent and PDMS were tuned to form the uniform PDMS dot array. The uniform PDMS dot array was printed with a diameter of around 50 µm, and the array of closely spaced green quantum dots (QDs) mixed with PDMS ink was also printed on the substrate uniformly. While the green QD-PDMS film was printed at a resolution of 1693 dpi, the uniformity was evaluated using the photoluminescence (PL) spectrum and color coordinate value.

摘要

喷墨打印法是一种在微尺度上沉积聚合物和功能性纳米颗粒的很有前景的方法。它可应用于制造多色聚合物发光二极管(polyLED)、聚合物基电子产品、多色颜色转换层和量子点发光二极管(QLED)。主要挑战之一是从稀聚合物溶液中打印出高分辨率的聚合物点。此外,目前打印的多色polyLED、QLED和多色颜色转换层的质量受到打印点不均匀性的限制。在本文中,聚二甲基硅氧烷(PDMS)因其高透明度、良好的折射率值、不易燃且柔韧性好的特性而被选作功能性聚合物。本文给出了形成均匀PDMS点阵列的最佳墨水。对溶剂和PDMS都进行了调整以形成均匀的PDMS点阵列。打印出了直径约为50 µm的均匀PDMS点阵列,并且还在基板上均匀地打印了与PDMS墨水混合的紧密排列的绿色量子点(QD)阵列。当以1693 dpi的分辨率打印绿色QD - PDMS薄膜时,使用光致发光(PL)光谱和颜色坐标值对均匀性进行了评估。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a973/9864531/0cdb45850492/polymers-15-00462-g001.jpg

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