Yaqoob Khurram, Amjad Izza, Munir Awan Muhammad Awais, Liaqat Usman, Zahoor Muhammad, Kashif Muhammad
School of Chemical and Materials Engineering, National University of Sciences and Technology, 44000 Islamabad, Pakistan.
Dept. Molecular Medicine, University of Oslo, 0315 Oslo, Norway.
ACS Omega. 2023 Jan 5;8(2):1876-1884. doi: 10.1021/acsomega.2c02340. eCollection 2023 Jan 17.
Titanium foams have potential applications in orthopedic and dental implants because of their low elastic modulus and good bone in-growth properties. In the present study, a novel method for the preparation of three-dimensional interconnected microporous titanium foams has been developed. This method is based on the insertion of a filler metal into the titanium metal by arc melting, followed by its removal by an electrochemical dealloying process for the development of foams. Complete removal of the filler metal by the electrochemical dealloying process was confirmed by an X-ray diffractometry (XRD) analysis, whereas scanning electron microscopy (SEM) analysis of the developed foams showed the development of interconnected porosity. Ti foams with different levels of porosities were successfully developed by varying the amount of the filler metal. Mechanical and thermal characterizations of the developed foams were carried out using compression testing and laser flash apparatus, respectively. The yield strength and elastic modulus of the developed foams were found to decrease by increasing the volume fraction of pores. The elastic modulus of the developed titanium foams (15.5-36 GPa) was found to be closer to that of human bones, whereas their yield strength (147-170 MPa) remained higher than that of human bones. It is therefore believed that the developed Ti foams can help in reducing the problem of stress shielding observed in orthopedic implants. The thermal diffusivity of the developed foams (4.3-0.69 mm/s) was found to be very close to that of human dentine.
泡沫钛因其低弹性模量和良好的骨向内生长特性,在骨科和牙科植入物方面具有潜在应用。在本研究中,已开发出一种制备三维互连微孔泡沫钛的新方法。该方法基于通过电弧熔炼将填充金属插入钛金属中,随后通过电化学脱合金工艺去除填充金属以形成泡沫。通过X射线衍射(XRD)分析证实了通过电化学脱合金工艺完全去除了填充金属,而对所制备泡沫的扫描电子显微镜(SEM)分析显示出互连孔隙的形成。通过改变填充金属的量成功制备了具有不同孔隙率水平的钛泡沫。分别使用压缩测试和激光闪光仪对所制备泡沫进行了力学和热学表征。发现所制备泡沫的屈服强度和弹性模量随着孔隙体积分数的增加而降低。所制备的泡沫钛的弹性模量(15.5 - 36 GPa)被发现更接近人体骨骼的弹性模量,而其屈服强度(147 - 170 MPa)仍高于人体骨骼的屈服强度。因此,据信所制备的钛泡沫有助于减少在骨科植入物中观察到的应力屏蔽问题。所制备泡沫的热扩散率(4.3 - 0.69 mm/s)被发现与人体牙本质的热扩散率非常接近。