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电化学有机反应:教程综述

Electrochemical organic reactions: A tutorial review.

作者信息

Lodh Joyeeta, Paul Shounik, Sun He, Song Luyang, Schöfberger Wolfgang, Roy Soumyajit

机构信息

Eco-Friendly Applied Materials Laboratory (EFAML), Materials Science Centre, Department of Chemical Sciences, Mohanpur Campus, Indian Institute of Science, Education and Research, Kolkata, West Bengal, India.

Institute of Organic Chemistry, Laboratory for Sustainable Chemistry and Catalysis (LSusCat), Johannes Kepler University (JKU), Linz, Austria.

出版信息

Front Chem. 2023 Jan 10;10:956502. doi: 10.3389/fchem.2022.956502. eCollection 2022.

Abstract

Although the core of electrochemistry involves simple oxidation and reduction reactions, it can be complicated in real electrochemical organic reactions. The principles used in electrochemical reactions have been derived using physical organic chemistry, which drives other organic/inorganic reactions. This review mainly comprises two themes: the first discusses the factors that help optimize an electrochemical reaction, including electrodes, supporting electrolytes, and electrochemical cell design, and the second outlines studies conducted in the field over a period of 10 years. Electrochemical reactions can be used as a versatile tool for synthetically important reactions by modifying the constant electrolysis current.

摘要

虽然电化学的核心涉及简单的氧化和还原反应,但在实际的电化学有机反应中可能会很复杂。电化学反应中使用的原理是从物理有机化学推导而来的,物理有机化学推动着其他有机/无机反应。本综述主要包括两个主题:第一个主题讨论有助于优化电化学反应的因素,包括电极、支持电解质和电化学池设计,第二个主题概述了该领域在10年期间进行的研究。通过改变恒定电解电流,电化学反应可以用作合成重要反应的通用工具。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b75d/9871948/75d4113ea3b3/fchem-10-956502-g001.jpg

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