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有机磷化合物电化学合成的最新进展。

Recent advances in the electrochemical synthesis of organophosphorus compounds.

作者信息

Kaboudin Babak, Behroozi Milad, Sadighi Sepideh, Asgharzadeh Fatemeh

机构信息

Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Gava Zang, Zanjan 45137-66731, Iran.

出版信息

Beilstein J Org Chem. 2025 Apr 16;21:770-797. doi: 10.3762/bjoc.21.61. eCollection 2025.

DOI:10.3762/bjoc.21.61
PMID:40276283
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12018900/
Abstract

In this review, we describe recent advances in electrochemical green methods for the synthesis of various organophosphorus compounds through the formation of phosphorus-carbon, phosphorus-nitrogen, phosphorus-oxygen, phosphorus-sulfur, and phosphorus-selenium bonds. The impact of different electrodes is also discussed in this matter. Graphite, platinum, RVC, and nickel electrodes have been used extensively for the electrochemical synthesis of organophosphorus compounds. The recent advances in the electrochemical synthesis of organophosphorus compounds have made this method a promising method for preparing various structures. This review is an introduction to encourage scientists to use electrosynthesis as a green, precise, and low-cost method to prepare phosphorous structures.

摘要

在本综述中，我们描述了通过形成碳 - 磷、氮 - 磷、氧 - 磷、硫 - 磷和硒 - 磷键来合成各种有机磷化合物的电化学绿色方法的最新进展。在这方面还讨论了不同电极的影响。石墨、铂、网状玻璃炭（RVC）和镍电极已广泛用于有机磷化合物的电化学合成。有机磷化合物电化学合成的最新进展使该方法成为制备各种结构的一种有前景的方法。本综述旨在鼓励科学家将电合成作为一种绿色、精确且低成本的方法来制备含磷结构。

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