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水相甲醇超声法制氢的批判性分析。

Critical Analysis of Hydrogen Production by Aqueous Methanol Sonolysis.

机构信息

Laboratory of Environmental Process Engineering, Department of Chemical Engineering, Faculty of Process Engineering, University Constantine, 3 Salah Boubnider, P.O. Box 72, 25000, Constantine, Algeria.

School of Chemistry, The University of Melbourne, Parkville, VIC, 3010, Australia.

出版信息

Top Curr Chem (Cham). 2023 Feb 2;381(2):9. doi: 10.1007/s41061-022-00418-1.

Abstract

Recently, several experimental and theoretical studies have demonstrated the feasibility of enhancing the sonochemical production of hydrogen via methanol pyrolysis within acoustic cavitation bubbles (i.e. sonolysis of aqueous methanol solution). This review includes both the experimental and theoretical achievements in the field of hydrogen production by methanol sonolysis. Additionally, the limits of the process's applicability and plausible solutions are highlighted. The impact of different parameters influencing the process performance is discussed. Finally, the effects of methanol concentration on the size distribution of active cavitation bubbles are analyzed.

摘要

最近,一些实验和理论研究表明,在声空化泡内(即甲醇水溶液的超声分解)通过甲醇热解增强超声化学产氢是可行的。本综述包括甲醇超声分解制氢领域的实验和理论成果。此外,还突出了该过程应用的局限性和可能的解决方案。讨论了影响过程性能的不同参数的影响。最后,分析了甲醇浓度对活性空化泡大小分布的影响。

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