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水相甲醇超声法制氢的批判性分析。

Critical Analysis of Hydrogen Production by Aqueous Methanol Sonolysis.

机构信息

Laboratory of Environmental Process Engineering, Department of Chemical Engineering, Faculty of Process Engineering, University Constantine, 3 Salah Boubnider, P.O. Box 72, 25000, Constantine, Algeria.

School of Chemistry, The University of Melbourne, Parkville, VIC, 3010, Australia.

出版信息

Top Curr Chem (Cham). 2023 Feb 2;381(2):9. doi: 10.1007/s41061-022-00418-1.

DOI:10.1007/s41061-022-00418-1
PMID:36729180
Abstract

Recently, several experimental and theoretical studies have demonstrated the feasibility of enhancing the sonochemical production of hydrogen via methanol pyrolysis within acoustic cavitation bubbles (i.e. sonolysis of aqueous methanol solution). This review includes both the experimental and theoretical achievements in the field of hydrogen production by methanol sonolysis. Additionally, the limits of the process's applicability and plausible solutions are highlighted. The impact of different parameters influencing the process performance is discussed. Finally, the effects of methanol concentration on the size distribution of active cavitation bubbles are analyzed.

摘要

最近,一些实验和理论研究表明,在声空化泡内(即甲醇水溶液的超声分解)通过甲醇热解增强超声化学产氢是可行的。本综述包括甲醇超声分解制氢领域的实验和理论成果。此外,还突出了该过程应用的局限性和可能的解决方案。讨论了影响过程性能的不同参数的影响。最后,分析了甲醇浓度对活性空化泡大小分布的影响。

相似文献

1
Critical Analysis of Hydrogen Production by Aqueous Methanol Sonolysis.水相甲醇超声法制氢的批判性分析。
Top Curr Chem (Cham). 2023 Feb 2;381(2):9. doi: 10.1007/s41061-022-00418-1.
2
Free radical formation by ultrasound in aqueous solutions. A spin trapping study.超声在水溶液中引发自由基形成的自旋捕获研究
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The size of active bubbles for the production of hydrogen in sonochemical reaction field.声化学反应场中用于制氢的活性气泡大小。
Ultrason Sonochem. 2016 Sep;32:320-327. doi: 10.1016/j.ultsonch.2016.03.026. Epub 2016 Mar 29.
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Sonochemistry of surfactants in aqueous solutions: an EPR spin-trapping study.水溶液中表面活性剂的声化学:电子顺磁共振自旋捕获研究
J Am Chem Soc. 2001 Nov 7;123(44):11010-9. doi: 10.1021/ja010857b.
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Sonochemistry of volatile and non-volatile solutes in aqueous solutions: e.p.r. and spin trapping studies.水溶液中挥发性和非挥发性溶质的声化学:电子顺磁共振和自旋捕获研究。
Ultrasonics. 1990 Sep;28(5):295-303. doi: 10.1016/0041-624x(90)90035-m.
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Sonochemistry of acetone and acetonitrile in aqueous solutions. A spin trapping study.水溶液中丙酮和乙腈的声化学。自旋捕获研究。
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Sonolysis of concentrated aqueous solutions of nonvolatile solutes: spin-trapping evidence for free radicals formed by pyrolysis.非挥发性溶质浓水溶液的声致分解:热解形成自由基的自旋捕获证据
Radiat Res. 1989 May;118(2):211-29.
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Radiat Res. 1988 Oct;116(1):56-73.
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Free radical generation by ultrasound in aqueous and nonaqueous solutions.超声在水溶液和非水溶液中产生自由基。
Environ Health Perspect. 1985 Dec;64:233-52. doi: 10.1289/ehp.8564233.
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Sonochemical free radical formation in aqueous solutions.水溶液中的声化学自由基形成
Fed Proc. 1986 Sep;45(10):2485-92.

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本文引用的文献

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Insight into the impact of excluding mass transport, heat exchange and chemical reactions heat on the sonochemical bubble yield: Bubble size-dependency.关于排除质量传递、热交换和化学反应热对声化学气泡产率的影响的见解:气泡尺寸依赖性。
Ultrason Sonochem. 2021 May;73:105511. doi: 10.1016/j.ultsonch.2021.105511. Epub 2021 Mar 11.
2
A comprehensive numerical analysis of heat and mass transfer phenomenons during cavitation sono-process.空化声处理过程中传热传质现象的综合数值分析
Ultrason Sonochem. 2021 May;73:105498. doi: 10.1016/j.ultsonch.2021.105498. Epub 2021 Feb 20.
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How do dissolved gases affect the sonochemical process of hydrogen production? An overview of thermodynamic and mechanistic effects - On the "hot spot theory".
Nanomaterials (Basel). 2024 Jan 23;14(3):239. doi: 10.3390/nano14030239.
溶解气体如何影响产氢的声化学过程?热力学和机理效应概述——关于“热点理论”
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4
Does power ultrasound (26 kHz) affect the hydrogen evolution reaction (HER) on Pt polycrystalline electrode in a mild acidic electrolyte?功率超声(26kHz)会对轻度酸性电解质中铂多晶电极上的析氢反应(HER)产生影响吗?
Ultrason Sonochem. 2020 Dec;69:105238. doi: 10.1016/j.ultsonch.2020.105238. Epub 2020 Jun 26.
5
Void fraction, number density of acoustic cavitation bubbles, and acoustic frequency: A numerical investigation.空隙率、声空化气泡的数密度和声频:一项数值研究。
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Oxygen-argon acoustic cavitation bubble in a water-methanol mixture: Effects of medium composition on sonochemical activity.氧气-氩气在水-甲醇混合物中的空化气泡:介质成分对声化学活性的影响。
Ultrason Sonochem. 2020 Mar;61:104811. doi: 10.1016/j.ultsonch.2019.104811. Epub 2019 Sep 28.
7
Ultrasonication-assisted synthesis of sphere-like strontium cerate nanoparticles (SrCeO NPs) for the selective electrochemical detection of calcium channel antagonists nifedipine.超声辅助合成类球形锶铈氧化物纳米粒子(SrCeO NPs)用于钙通道拮抗剂硝苯地平的选择性电化学检测。
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8
Depth effect on the inertial collapse of cavitation bubble under ultrasound: Special emphasis on the role of the wave attenuation.超声空化泡惯性坍塌的深度效应:特别强调波衰减的作用。
Ultrason Sonochem. 2018 Nov;48:136-150. doi: 10.1016/j.ultsonch.2018.05.004. Epub 2018 May 21.
9
Modeling of sonochemistry in water in the presence of dissolved carbon dioxide.水中存在溶解二氧化碳时的声化学模拟。
Ultrason Sonochem. 2018 Jul;45:17-28. doi: 10.1016/j.ultsonch.2018.02.044. Epub 2018 Mar 6.
10
A model for the effect of bulk liquid viscosity on cavitation bubble dynamics.一种关于大量液体粘度对空化气泡动力学影响的模型。
Phys Chem Chem Phys. 2017 Aug 9;19(31):20635-20640. doi: 10.1039/c7cp03194g.