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评估在水处理和储存过程中,从各种管材和滤水器元件迁移至饮用水中的邻苯二甲酸酯类物质对人体的暴露情况。

Assessing human exposure to phthalate esters in drinking water migrated from various pipe materials and water filter elements during water treatments and storage.

作者信息

Zhang Liqun, Ren Ren, He Huali, Liu Shaoying

机构信息

Hangzhou Center for Disease Control and Prevention, Hangzhou, 310021, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2023 Apr;30(16):47832-47843. doi: 10.1007/s11356-023-25633-1. Epub 2023 Feb 7.

DOI:10.1007/s11356-023-25633-1
PMID:36749517
Abstract

Plastic water-supply pipes and filter element are frequently used in municipal water supply systems. Leaching of phthalate esters (PAEs) from these pipes and filter elements to drinking water has become a common concern among the public. In this study, the migrations of 16 phthalate esters (PAEs) in seven different kinds of water-supply product materials were investigated. Di-n-butyl phthalate (DBP) had the highest detection frequency of 54.4% in the water leaching samples of various water supply pipes and water filter elements samples, followed by Diisobutyl phthalate (DIBP, 46/90, 51.1%). The maximum detected concentration level for di(2-ethylhexyl) phthalate (DEHP), diethyl phthalate (DEP), and DBP in the leaching experiment was below the regulatory limit values of 8 µg/L, 300 µg/L, and 3 µg/L for each compound in China standards for drinking water quality. The increasing of the water temperature, the lower pH of the water, and the increasing of the leaching time will increase the migration of PAEs from plastic pipes into water. The chronic daily intake of children aged < 1-12 years to PAEs through drinking water was higher than the rest of the population groups. Carcinogenic risks (CR) of DEHP via drinking water were neglectable for most groups of people, while for young children with age of 1-2 years old, the CR is an acceptable risk.

摘要

塑料供水管和滤芯在市政供水系统中经常使用。这些管材和滤芯中的邻苯二甲酸酯(PAEs)向饮用水中的浸出已成为公众普遍关注的问题。本研究调查了16种邻苯二甲酸酯(PAEs)在7种不同供水产品材料中的迁移情况。在各种供水管和滤水器滤芯样品的水浸出样品中,邻苯二甲酸二丁酯(DBP)的检测频率最高,为54.4%,其次是邻苯二甲酸二异丁酯(DIBP,46/90,51.1%)。在浸出实验中,邻苯二甲酸二(2-乙基己基)酯(DEHP)、邻苯二甲酸二乙酯(DEP)和DBP的最大检测浓度水平低于中国饮用水水质标准中各化合物8 μg/L、300 μg/L和3 μg/L的规定限值。水温升高、水的pH值降低以及浸出时间增加都会增加PAEs从塑料管向水中的迁移。<1至12岁儿童通过饮用水对PAEs的慢性每日摄入量高于其他人群。对于大多数人群,通过饮用水摄入DEHP的致癌风险(CR)可忽略不计,而对于1至2岁的幼儿,该CR是可接受的风险。

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