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使用皂苷制备β-环糊精/多糖泡沫

Preparation of β-cyclodextrin/polysaccharide foams using saponin.

作者信息

Petitjean Max, Isasi José Ramón

机构信息

Department of Chemistry. University of Navarra. 31080 Pamplona, Spain.

出版信息

Beilstein J Org Chem. 2023 Jan 24;19:78-88. doi: 10.3762/bjoc.19.7. eCollection 2023.

Abstract

Cyclodextrins, cyclic oligosaccharides with a hydrophobic cavity that form inclusion complexes with nonpolar molecules, can be used to functionalize other polysaccharides. Xanthan gum, locust bean gum or chitosan can be crosslinked using citric acid in the presence of β-cyclodextrin to produce insoluble matrices. In this work, polymeric foams based on those polysaccharides and saponin have been prepared using a green synthesis method to increase the porosity of the matrices. The saponin of soapbark () has been used to obtain foams using different procedures. The influence of the synthesis path on the porosity of the materials and their corresponding sorption capacities in the aqueous phase were evaluated.

摘要

环糊精是一种具有疏水空腔的环状低聚糖,能与非极性分子形成包合物,可用于其他多糖的功能化。在β-环糊精存在下,可用柠檬酸使黄原胶、刺槐豆胶或壳聚糖交联,以制备不溶性基质。在这项工作中,已采用绿色合成方法制备了基于这些多糖和皂苷的聚合物泡沫,以增加基质的孔隙率。皂树的皂苷已被用于通过不同程序制备泡沫。评估了合成路径对材料孔隙率及其在水相中的相应吸附容量的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9896/9887783/656aecfb7d62/Beilstein_J_Org_Chem-19-78-g002.jpg

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