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原位制备聚丙稀复合材料中的 ZnO 及其他含 Zn(II)化合物的方法。

An In-Situ Fabrication Method of ZnO and Other Zn(II) Compounds Containing Polypropylene Composites.

机构信息

Panamedica Maciej Michalik, Józefa Ignacego Kraszewskiego 18/7, 15-025 Białystok, Poland.

Doctoral School of Exact and Natural Sciences, University of Białystok, Ciołkowskiego 1K, 15-245 Białystok, Poland.

出版信息

Int J Mol Sci. 2023 Jan 25;24(3):2357. doi: 10.3390/ijms24032357.

Abstract

This study investigated the methods of preparation of zinc oxide-polypropylene nanocomposites and their antibacterial properties. Seven solutions with ZnO nanoparticles or zinc ions were formulated as a PP additive. Two methods of ZnO NPs syntheses were carried out: (1) a modified hydrothermal method where a water solution of zinc acetate dihydrate, PEI, and ammonia were mixed with a final pH 11; (2) a thermal decomposition of a water solution of zinc acetate in the presence of PEI and ammonia using a two-screw extruder. During the experiments, the influence of various amounts of particle stabilizer, heating of the solutions, and the temperatures of the syntheses were examined. As a result, the simultaneous crystallization of ZnO in the extrusion process confirmed this method's attractiveness from the application point of view. Fabricated PP-ZnO composite shows antibacterial properties against , , and .

摘要

本研究探讨了制备氧化锌-聚丙烯纳米复合材料的方法及其抗菌性能。将七种含有氧化锌纳米粒子或锌离子的溶液配制成聚丙烯添加剂。采用两种方法合成 ZnO NPs:(1)改良水热法,将二水合醋酸锌、PEI 和氨水溶液混合,最终 pH 值为 11;(2)在 PEI 和氨水溶液存在下,使用双螺杆挤出机热分解二水合醋酸锌。在实验中,考察了不同量的颗粒稳定剂、溶液加热和合成温度的影响。结果表明,在挤出过程中氧化锌的同时结晶从应用的角度证实了该方法的吸引力。制备的 PP-ZnO 复合材料对 、 、 和 具有抗菌性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6f77/9916773/26e14941aca1/ijms-24-02357-g001.jpg

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