Baskakov Sergey A, Baskakova Yulia V, Kabachkov Eugene N, Dvoretskaya Elizaveta V, Krasnikova Svetlana S, Korepanov Vitaly I, Michtchenko Alexandre, Shulga Yury M
Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432 Moscow, Russia.
Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, 142432 Moscow, Russia.
Nanomaterials (Basel). 2023 Jan 30;13(3):553. doi: 10.3390/nano13030553.
Thermally stable films were obtained from a water-based polyurethane (PU) dispersion with small (0.1-1.5 wt.%) additions of graphene oxide (GO). The films were studied through elemental analysis, X-ray photoelectron spectroscopy, differential thermogravimetry, and Raman spectroscopy. It was found that the introduction of GO into a PU matrix was accompanied by a partial reduction in graphene oxide nanosheet and an increase in the concentration of defects in GO structure. It has been also established that the [C/N] ratio in the near-surface layer of PU/GO composite films grows with an increase in the content of graphene oxide in the composite films.
通过向水基聚氨酯(PU)分散体中添加少量(0.1 - 1.5重量%)的氧化石墨烯(GO)获得了热稳定薄膜。通过元素分析、X射线光电子能谱、差示热重分析和拉曼光谱对薄膜进行了研究。发现将GO引入PU基体时,氧化石墨烯纳米片会发生部分还原,且GO结构中的缺陷浓度增加。还确定了PU/GO复合薄膜近表层中的[C/N]比随复合薄膜中氧化石墨烯含量的增加而增大。