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基于聚偏氟乙烯/银纳米颗粒/碳化钛复合材料的具有增强压电性能的近场电纺纤维用于自供电可穿戴传感器。

PVDF/AgNP/MXene composites-based near-field electrospun fiber with enhanced piezoelectric performance for self-powered wearable sensors.

作者信息

Pan Cheng-Tang, Dutt Karishma, Kumar Amit, Kumar Rahul, Chuang Cheng-Hsin, Lo Yi-Ting, Wen Zhi-Hong, Wang Chien-Shu, Kuo Shiao-Wei

机构信息

Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-sen University, Kaohsiung 80424, Taiwan.

Institute of Advanced Semiconductor Packaging and Testing, College of Semiconductor and Advanced Technology Research, National Sun Yat-sen University, Kaohsiung 80424, Taiwan.

出版信息

Int J Bioprint. 2022 Nov 24;9(1):647. doi: 10.18063/ijb.v9i1.647. eCollection 2023.

DOI:10.18063/ijb.v9i1.647
PMID:36844238
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9947487/
Abstract

336MXenes, as highly electronegative and conductive two-dimensional nanomaterials, are extensively studied for their use in sensors and flexible electronics. In this study, near-field electrospinning was used to prepare a new poly(vinylidene difluoride) (PVDF)/Ag nanoparticle (AgNP)/MXene composite nanofiber film as a self-powered flexible human motion-sensing device. The composite film displayed highly piezoelectric properties with the presence of MXene. Scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy revealed that the intercalated MXene in the composite nanofibers was evenly spread out, which not only prevented the aggregation of MXene but also enabled the composite materials to form self-reduced AgNPs. The prepared PVDF/AgNP/MXene fibers displayed exceptional stability and excellent output performance, enabling their use for energy harvesting and powering light-emitting diodes. The doping of MXene/AgNPs increased the electrical conductivity of the PVDF material, improved its piezoelectric properties, and enhanced the piezoelectric constant of PVDF piezoelectric fibers, thereby allowing the production of flexible, sustainable, wearable, and self-powered electrical devices.

摘要

336MXenes作为具有高电负性和导电性的二维纳米材料,因其在传感器和柔性电子器件中的应用而受到广泛研究。在本研究中,采用近场静电纺丝法制备了一种新型的聚偏氟乙烯(PVDF)/银纳米颗粒(AgNP)/MXene复合纳米纤维膜,作为一种自供电的柔性人体运动传感装置。复合膜在存在MXene的情况下表现出高压电性能。扫描电子显微镜、X射线衍射和傅里叶变换红外光谱表明,复合纳米纤维中插层的MXene均匀分散,这不仅防止了MXene的聚集,还使复合材料形成了自还原的AgNPs。制备的PVDF/AgNP/MXene纤维表现出优异的稳定性和出色的输出性能,使其可用于能量收集和为发光二极管供电。MXene/AgNPs的掺杂提高了PVDF材料的电导率,改善了其压电性能,并增强了PVDF压电纤维的压电常数,从而能够生产出柔性、可持续、可穿戴和自供电的电子器件。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aff/9947487/3ab271b9b3a1/IJB-9-1-647-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aff/9947487/7a3f86ba29ec/IJB-9-1-647-g007.jpg
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