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城市及其周边多污染源土壤重金属的影响因素识别与嵌套结构分析。

Influencing factors identification and the nested structure analysis of heavy metals in soils in entire city and surrounding the multiple pollution sources.

机构信息

Institute of Resources and Environment, Beijing Academy of Science and Technology, Beijing Key Laboratory of Remediation of Industrial Pollution Sites, Beijing 100089, China.

Institute of Resources and Environment, Beijing Academy of Science and Technology, Beijing Key Laboratory of Remediation of Industrial Pollution Sites, Beijing 100089, China.

出版信息

J Hazard Mater. 2023 May 5;449:130961. doi: 10.1016/j.jhazmat.2023.130961. Epub 2023 Feb 8.

Abstract

Identifying the sources of pollutants and analyzing the nested structure of heavy metals is vital for the prevention and control of soil pollution. However, there is a lack of research on comparison the main sources and the nested structure at different scales. In this study, two spatial extent scales were taken as the research objects, the results showed that, (1) the point exceeding standard rate of As, Cr, Ni, and Pb is higher at the entire city scale; (2) As and Pb, while Cr, Ni, and Zn, have weaker spatial variability at the entire scale and surrounding the pollution sources, respectively; (3) the contribution of the larger structure of Cr and Ni, while Cr, Ni, and Zn, at the entire scale and surrounding the pollution sources, respectively, is bigger to the total variability. The representation of semivariogram is better when the general spatial variability is weaker and the contribution of the smaller structure is lower; (4) various factors with different influencing distance could lead to nested structure even at a small extent spatial scale. The results provide a basis for the determination of remediation and prevention objectives at different spatial scales.

摘要

识别污染物的来源并分析重金属的嵌套结构对于土壤污染的预防和控制至关重要。然而,对于不同尺度下主要污染源和嵌套结构的比较研究还很缺乏。在这项研究中,我们以两个空间范围尺度作为研究对象,结果表明:(1) 在整个城市尺度上,As、Cr、Ni 和 Pb 的超标点率更高;(2) 在整个尺度和污染源周围,As 和 Pb 的空间变异性较弱,而 Cr、Ni 和 Zn 则分别较弱;(3) 在整个尺度和污染源周围,Cr 和 Ni 的较大结构对总变异性的贡献更大,而 Cr、Ni 和 Zn 的较大结构对总变异性的贡献更大;(4) 当一般空间变异性较弱且较小结构的贡献较低时,半变异函数的表示效果更好;(5) 具有不同影响距离的各种因素可能导致嵌套结构,即使在较小的空间尺度上也是如此。研究结果为不同空间尺度下确定修复和预防目标提供了依据。

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