Anyfantis Dimitrios I, Ballani Camillo, Kanistras Nikos, Barnasas Alexandros, Tsiaoussis Ioannis, Schmidt Georg, Papaioannou Evangelos Th, Poulopoulos Panagiotis
Department of Materials Science, School of Natural Sciences, University of Patras, 26504 Patras, Greece.
Institut für Physik, Martin-Luther Universität Halle Wittenberg, Von-Danckelmann-Platz 3, 06120 Halle, Germany.
Materials (Basel). 2023 Feb 7;16(4):1378. doi: 10.3390/ma16041378.
Co/CoO multilayers are fabricated by means of radio-frequency magnetron sputtering. For the formation of each multilayer period, a Co layer is initially produced followed by natural oxidation. Platinum is used not only as buffer and capping layers, but also in the form of intermediate ultrathin layers to enhance perpendicular magnetic anisotropy. Three samples are compared with respect to the magnetic anisotropies and exchange bias between 4-300 K based on superconducting quantum interference device magnetometry measurements. Two of the multilayers are identical Co/CoO/Pt ones; one of them, however, is grown on a Co/Pt "magnetic substrate" to induce perpendicular magnetic anisotropy via exchange coupling through an ultrathin Pt intermediate layer. The third multilayer is of the form Co/CoO/Co/Pt. The use of a "magnetic substrate" results in the observation of loops with large remanence when the field applies perpendicular to the film plane. The CoO/Co interfaces lead to a significant exchange bias at low temperatures after field cooling. The largest exchange bias was observed in the film with double Co/CoO/Co interfaces. Consequently, significant perpendicular anisotropy coexists with large exchange bias, especially at low temperatures. Such samples can be potentially useful for applications related to spintronics and magnetic storage.
通过射频磁控溅射制备了Co/CoO多层膜。对于每个多层周期的形成,首先制备Co层,然后进行自然氧化。铂不仅用作缓冲层和覆盖层,还以中间超薄层的形式使用,以增强垂直磁各向异性。基于超导量子干涉器件磁力测量,对三个样品在4 - 300 K之间的磁各向异性和交换偏置进行了比较。其中两个多层膜是相同的Co/CoO/Pt结构;然而,其中一个生长在Co/Pt“磁性衬底”上,通过超薄Pt中间层的交换耦合诱导垂直磁各向异性。第三个多层膜的结构为Co/CoO/Co/Pt。当磁场垂直于膜平面施加时,使用“磁性衬底”会观察到具有大剩磁的磁滞回线。在磁场冷却后,CoO/Co界面在低温下导致显著的交换偏置。在具有双Co/CoO/Co界面的薄膜中观察到最大的交换偏置。因此,显著的垂直各向异性与大的交换偏置共存,特别是在低温下。这样的样品在与自旋电子学和磁存储相关的应用中可能具有潜在用途。